Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1548-1556.DOI: 10.6023/cjoc201903012 Previous Articles     Next Articles

Special Issue: 金属有机化学



单贺a, 伶俐a, 胡剑锋a, 张浩a,b   

  1. a 内蒙古大学化学化工学院 呼和浩特 010021;
    b 内蒙古自治区精细有机合成重点实验室 呼和浩特 010021
  • 收稿日期:2019-03-06 修回日期:2019-04-26 发布日期:2019-05-06
  • 通讯作者: 张浩
  • 基金资助:


Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

Shan Hea, Ling Lia, Hu Jianfenga, Zhang Haoa,b   

  1. a College of Chemical & Chemical Engineering, Inner Mongolia University, Hohhot 010021;
    b Inner Mongolia Key Laboratory of Fine Organic Synthesis, Hohhot 010021
  • Received:2019-03-06 Revised:2019-04-26 Published:2019-05-06
  • Contact: 10.6023/cjoc201903012
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21861028) and the Natural Science Foundation of Inner Mongolia (No. 2017MS0206).

The chiral Cp ligands as stereocontrolling element of asymmetric catalytic reactions have attracted increasing attention. Particularly, designing and synthesizing more versatile chiral Cp ligands became one of the most interested research focuses in asymmetric catalysis. The complexes of various chiral Cp ligands with different transition metals that advanced in recent years, and the applications of these complexes in catalytic asymmetric reactions are reviewed in this paper.

Key words: cyclopentadienyl ligands, asymmetric catalytic reactions, transition metal catalysis, synthesis