Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (3): 598-613.DOI: 10.6023/cjoc201909030 Previous Articles     Next Articles

Special Issue: 有机光催化合辑

可见光诱导烷基羧酸及其衍生物的脱羧偶联反应研究进展

周明东, 覃丕涛, 经理珂, 孙京, 杜海武   

  1. 辽宁石油化工大学化学化工与环境学部 辽宁抚顺 113001
  • 收稿日期:2019-09-18 修回日期:2019-11-01 发布日期:2020-04-02
  • 通讯作者: 周明东, 孙京 E-mail:mingdong.zhou@lnpu.edu.cn;sungjing@lnpu.edu.cn
  • 基金资助:
    辽宁省自然科学基金博士启动(No.20180540085)资项目.

Progress in Photoinduced Decarboxylative Radical Cross-Coupling of Alkyl Carboxylic Acids and Their Derivatives

Zhou Mingdong, Qin Pitao, Jing Like, Sun Jing, Du Haiwu   

  1. College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113001
  • Received:2019-09-18 Revised:2019-11-01 Published:2020-04-02
  • Supported by:
    Project supported by the Doctoral Start-up Foundation of Liaoning Province (No. 20180540085).

Alkyl carboxylic acids are among the most ubiquitous organic molecules found in nature. The reactions using abundant carboxylic acid and its derivatives as starting materials deserve widespread attention over the world. They are often easy to generate alkyl radical by photoredox catalysis under mild conditions for building various chemical bonds in organic chemistry. Based on the reaction modes, decarboxylation of alkylcarboxylic acids and their derivatives, the recent progress in decarboxylation of alkylcarboxylic acids and their derivatives under visible light is reviewed.

Key words: photocatalysis, decarboxylative, alkyl radical