Recent Progress in Fluorescent Probes for the Detection of Ferrous Ion

doi:10.6023/cjoc202006003

Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (1): 229-240.DOI: 10.6023/cjoc202006003 Previous Articles Next Articles

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亚铁离子荧光探针的研究进展

马素芳^a^,^c, 余强^b, 陆利^a, 李丽红^a, 刘文^a^,^c, 武志芳^b^,^c^,^*(), 李思进^b^,^c^,^*()

a 山西医科大学基础医学院太原 030001
b 山西医科大学医学影像学院太原 030001
c 山西医科大学第一医院核医学科太原 030001

收稿日期:2020-06-02 修回日期:2020-07-10 发布日期:2020-08-01
通讯作者: 武志芳, 李思进
作者简介:
* Corresponding authors. E-mail: wuzhifang01@163.com; lisjnm123@163.com
基金资助:
山西省青年科技研究基金(201901D211348); 山西省高等学校科技创新(2019L0409); 山西省高等学校科技创新(2019L0444); 山西医科大学博士启动基金(BS03201609)

Recent Progress in Fluorescent Probes for the Detection of Ferrous Ion

Sufang Ma^a^,^c, Qiang Yu^b, Li Lu^a, Lihong Li^a, Wen Liu^a^,^c, Zhifang Wu^b^,^c^,^*(), Sijin Li^b^,^c^,^*()

a School of Basic Medical Science, Shanxi Medical University, Taiyuan 030001
b Medical Imaging Department, Shanxi Medical University, Taiyuan 030001
c Department of Nuclear Medicine, First Hospital of Shanxi Medical University, Taiyuan 030001

Received:2020-06-02 Revised:2020-07-10 Published:2020-08-01
Contact: Zhifang Wu, Sijin Li
Supported by:
the Youth Science Foundation of Shanxi Province(201901D211348); the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province(2019L0409); the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province(2019L0444); the Ph. D Startup Fund of Shanxi Medical University(BS03201609)

Irons, as the most abundant transition metal in living system, play an irreplaceable role in many physiological and pathological processes. The misregulation of Fe ²⁺ homeostasis not only affects the occurence and delelopment of various diseases, such as cancer, cardiovascular disease and neurodegenerative disorders, but also induces ferroptosis. Although two forms of iron (Fe ²⁺ and Fe ³⁺) exist in cells, reducing microenvironment of cells makes it exist mainly in the form of Fe ²⁺. Therefore, developing a sensitive approach for Fe ²⁺ is particularly important because it may contribute to the in-depth understanding of the relationship between Fe ²⁺ and human health and disease. In recent years, with the rapid development of fluorescent imaging technique, fluorescent probes for the sensitive detection of Fe ²⁺ have attracted great interest. Fe ²⁺ fluorescent probes reported in the last ten years are summarized, according to probes design, sensing mechanisms with Fe ²⁺, optical properties and biological application. In addition, the development prospect of Fe ²⁺ fluorescent probes is predicted.

Key words: s ferrous ion, fluorescent probe, fluorescent imaging

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Sufang Ma, Qiang Yu, Li Lu, Lihong Li, Wen Liu, Zhifang Wu, Sijin Li. Recent Progress in Fluorescent Probes for the Detection of Ferrous Ion[J]. Chinese Journal of Organic Chemistry, 2021, 41(1): 229-240.

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Fig. & Tab. 9

References 60

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探针	λ _ex/nm	λ _em/nm	响应方式	应用	Ref.
1	555	575	off-on (30倍)	HepG2, MCF-7细胞, 小鼠肾癌变模型组织	[33]
2	555	575	off-on (60倍)	HepG2细胞	[34~35]
3	405	495	off-on (10倍)	HepG2细胞	[36]
4	510	535	off-on (30倍)	HepG2细胞	[36]
5	645	660	off-on (60倍)	HepG2细胞	[36]
6	540	575	off-on (20倍)	HepG2细胞, 海马神经元	[37]
7	510	535	off-on (100倍)	HepG2细胞	[38]
8	—	—	off-on	HepG2, HEK293细胞	[38]
9	550	690	off-on (7倍)	MCF-7细胞	[39]
10	580	630	off-on (50倍)	HeLa细胞, 鼠模型	[40]
11	505	700	off-on (120倍)	MCF-7, HeLa, HEK-293T和L02细胞, 鼠模型	[41]
12	395	540	off-on (130倍)	—	[42]
13	350	489	off-on (5倍)	Kyse180细胞	[43]
14		580	off-on (2.5倍)	Ws1细胞	[44]
15	450	540	off-on (5倍)	HeLa细胞, 斑马鱼	[45]
16	404/496	508	off-on (6倍)	HepG2, C3A细胞	[46]
17	560	690	off-on (4倍)	HL-7702, 鼠模型	[47]
18	—	—	off-on无氧1.7倍, 有氧30倍	PC3-luc, MDA-MB-231-luc, HEK-293和LNCaP-luc细胞	[48]
19	557	560	off-on (3倍)	水	[49]
20	435	544	off-on (27倍)	星形胶质细胞, 小鼠缺血性脑组织	[50]
21	369	452	off-on (24倍)	HepG2细胞	[51]
22	510	571	off-on (60倍)	RAW264.7细胞	[52]
23	445	550	off-on (16倍)	HL-7702细胞	[53]
24	225/300	370	off-on (1.7倍)	番茄汁, 黑巧克力, 市售药物, 自来水	[54]
25	352	450	off-on (15倍)	—	[55]
26	—	—	on-off	MCF-7细胞	[27]
27	—	—	on-off	HepG2、HL-7702和RAW 264.7	[56]
28	—	—	on-off	阿尔兹海默症雌性肉瘤小鼠模型	[29]
29	—	—	免疫荧光法	U2OS和PC-3细胞	[57]
30	494/545	515/556	比率法	HEK-293, MCF-10A, MDA-MB-231和U2OS细胞	[58]
31	485/569	507/635	比率法	HL-7702细胞	[59]
32	—	—	比率法	乳酸亚铁口服液	[28]
33	552	622/820	比率法	HepG2细胞、缺血性损伤神经元	[60]

探针	λ _ex/nm	λ _em/nm	响应方式	应用	Ref.
1	555	575	off-on (30倍)	HepG2, MCF-7细胞, 小鼠肾癌变模型组织	[33]
2	555	575	off-on (60倍)	HepG2细胞	[34~35]
3	405	495	off-on (10倍)	HepG2细胞	[36]
4	510	535	off-on (30倍)	HepG2细胞	[36]
5	645	660	off-on (60倍)	HepG2细胞	[36]
6	540	575	off-on (20倍)	HepG2细胞, 海马神经元	[37]
7	510	535	off-on (100倍)	HepG2细胞	[38]
8	—	—	off-on	HepG2, HEK293细胞	[38]
9	550	690	off-on (7倍)	MCF-7细胞	[39]
10	580	630	off-on (50倍)	HeLa细胞, 鼠模型	[40]
11	505	700	off-on (120倍)	MCF-7, HeLa, HEK-293T和L02细胞, 鼠模型	[41]
12	395	540	off-on (130倍)	—	[42]
13	350	489	off-on (5倍)	Kyse180细胞	[43]
14		580	off-on (2.5倍)	Ws1细胞	[44]
15	450	540	off-on (5倍)	HeLa细胞, 斑马鱼	[45]
16	404/496	508	off-on (6倍)	HepG2, C3A细胞	[46]
17	560	690	off-on (4倍)	HL-7702, 鼠模型	[47]
18	—	—	off-on无氧1.7倍, 有氧30倍	PC3-luc, MDA-MB-231-luc, HEK-293和LNCaP-luc细胞	[48]
19	557	560	off-on (3倍)	水	[49]
20	435	544	off-on (27倍)	星形胶质细胞, 小鼠缺血性脑组织	[50]
21	369	452	off-on (24倍)	HepG2细胞	[51]
22	510	571	off-on (60倍)	RAW264.7细胞	[52]
23	445	550	off-on (16倍)	HL-7702细胞	[53]
24	225/300	370	off-on (1.7倍)	番茄汁, 黑巧克力, 市售药物, 自来水	[54]
25	352	450	off-on (15倍)	—	[55]
26	—	—	on-off	MCF-7细胞	[27]
27	—	—	on-off	HepG2、HL-7702和RAW 264.7	[56]
28	—	—	on-off	阿尔兹海默症雌性肉瘤小鼠模型	[29]
29	—	—	免疫荧光法	U2OS和PC-3细胞	[57]
30	494/545	515/556	比率法	HEK-293, MCF-10A, MDA-MB-231和U2OS细胞	[58]
31	485/569	507/635	比率法	HL-7702细胞	[59]
32	—	—	比率法	乳酸亚铁口服液	[28]
33	552	622/820	比率法	HepG2细胞、缺血性损伤神经元	[60]

亚铁离子荧光探针的研究进展

Recent Progress in Fluorescent Probes for the Detection of Ferrous Ion

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