Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (11): 3605-3619.DOI: 10.6023/cjoc202006033 Previous Articles     Next Articles


史敦发a,b, 王露a, 夏春谷a, 刘超a   

  1. a 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000;
    b 中国科学院大学 北京 100049
  • 收稿日期:2020-06-18 修回日期:2020-08-29 发布日期:2020-09-09
  • 通讯作者: 刘超
  • 基金资助:

Recent Advances in Visible-Light-Promoted Transformation of Alkyl Boron Compounds

Shi Dunfaa,b, Wang Lua, Xia Chungua, Liu Chaoa   

  1. a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
    b University of Chinese Academy of Sciences, Beijing 100049
  • Received:2020-06-18 Revised:2020-08-29 Published:2020-09-09
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21673261, 91745110, 21872156), the Natural Science Foundation of Jiangsu Province (Nos. BK20190002, BK20181194) and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (No. 2018458).

Organoboron compounds are valuable synthetic intermediates and widely used in the synthesis of medicine, pesticide and organic optoelectronic materials due to their extensive resouce and highly transformable ability. Among various organoboron compounds, the synthesis and transformation of alkylboron compounds have attracted much attention. As a sustainable and green energy, visible light shows an important effect in organic systhesis. Tetracoordinated alkylboron compounds could occur single electron transfer (SET) process to generate alkyl radical for further transformations. Herein, the recent advances in the photoinduced transformation of alkyl boron compounds are summarized.

Key words: boron, photocatalysis, radical, single electron transfer