Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (1): 171-184.DOI: 10.6023/cjoc202006064 Previous Articles     Next Articles

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非光催化与电化学体系下有机硫试剂参与的烯烃构建C—S键研究进展

王柏文a,b, 周永军a, 罗时荷a,b,*(), 罗晓燕a, 陈伟清a, 杨诗敏a, 汪朝阳a,b,*()   

  1. a 华南师范大学化学学院 教育部环境理论化学重点实验室 广州市生物医药分析化学重点实验室 广州 510006
    b 华南理工大学 广东省功能分子工程重点实验室 广州 510640
  • 收稿日期:2020-06-29 修回日期:2020-07-24 发布日期:2020-08-11
  • 通讯作者: 罗时荷, 汪朝阳
  • 作者简介:
    * Corresponding authors. E-mail: ;
  • 基金资助:
    广州市科技计划科学研究专项(201607010251); 广东省科技计划(2017A010103016); 广东省功能分子工程重点实验室开放课题(2017kf01)

Research Progress in CS Bond Formation Reaction of Olefins with Organic Sulfur Reagents under Photocatalyst-Free and Non-Electrochemical Conditions

Bowen Wanga,b, Yongjun Zhoua, Shihe Luoa,b,*(), Xiaoyan Luoa, Weiqing Chena, Shimin Yanga, Zhaoyang Wanga,b,*()   

  1. a Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine, School of Chemistry, South China Normal University, Guangzhou 510006
    b Key Lab of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510640
  • Received:2020-06-29 Revised:2020-07-24 Published:2020-08-11
  • Contact: Shihe Luo, Zhaoyang Wang
  • Supported by:
    the Science and Technology Project Scientific Special of Guangzhou City(201607010251); the Guangdong Provincial Science and Technology Project(2017A010103016); the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province(2017kf01)

Olefin is an important synthetic synthon, and its concise and efficient transformation has been a research hotspot in the field of organic synthesis. In recent years, the C—S bond formation based on the olefin skeleton has received particular attention from scientists. Alkenes can react with common organic sulfur-containing reagents, including thiol, disulfide, sulfoxide, sulfonyl hydrazide, sulfonyl chloride, sodium sulfinate and other kinds of organosulfur reagents to build C—S bonds at the α-position or β-position of olefin to synthesize sulfide, sulfoxide or sulfone. Thus, according to the different classification of the used organosulfur reagents, the recent research progresses in C—S bond formation reaction of olefins with organic sulfur reagents under photocatalyst-free conditions and non-electrochemical method is summarized. In the future, among the researches on the C—S bond formation reactions of olefins with inexpensive organosulfur reagents, asymmetrical synthesis and various difunctionalizations are still promising directions.

Key words: alkene, C—S bond formation reaction, thiol, sodium sulfinate, aryl ethylene, thioetherification, difunctionalization