Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4725-4731.DOI: 10.6023/cjoc202111014 Previous Articles     Next Articles

ARTICLES

可见光介导无金属的苯乙酸衍生物脱羧氘代

何宇航, 杨慧, 高冬旭, 马嘉慧, 邵亚敏, 安光辉*(), 李光明*()   

  1. 黑龙江大学化学化工与材料学院 功能无机材料化学重点实验室 哈尔滨 150080
  • 收稿日期:2021-11-06 修回日期:2021-12-11 发布日期:2021-12-15
  • 通讯作者: 安光辉, 李光明
  • 基金资助:
    国家自然科学基金(21502046)

Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid

Yuhang He, Hui Yang, Dongxu Gao, Jiahui Ma, Yamin Shao, Guanghui An(), Guangming Li()   

  1. Key Laboratory of Functional Inorganic Material Chemistry, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080
  • Received:2021-11-06 Revised:2021-12-11 Published:2021-12-15
  • Contact: Guanghui An, Guangming Li
  • Supported by:
    National Natural Science Foundation of China(21502046)

A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.

Key words: photochemistry, metal-free, decarboxylation, deuteration