A new chiral β-sulfiny dienophile for asymmetric diels-alder reaction

Chin. J. Org. Chem. ›› 1993, Vol. 13 ›› Issue (2): 183-185. Previous Articles Next Articles

Original Articles

新的手性β-亚磺酰亲双烯体用于不对称Diels-Alder反应

杨登贵;HUNG SHUN-MING;CHEN CHIN-ZON;蒋跃忠;密爱巧

中央大学化学系;中国科学院成都有机化学研究所

发布日期:1993-04-25

A new chiral β-sulfiny dienophile for asymmetric diels-alder reaction

YANG DENGGUI;HUNG SHUN-MING;CHEN CHIN-ZON;JIANG YUEZHONG;MI AIQIAO

Published:1993-04-25

Abstract

Reaction of a chiral cis-β-sulfinylacrylate, prepared from (1R, 2S, 3R)-3-mercapto-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, and cyclopentadiene produced Diels-Alder cycloadducts with extremely high diastereoselectivity.

Key words: ALCOHOL, MERCAPTAN, SULFINYL GROUP, DIENE SYNTHESIS, PROPENOIC ACID ESTER, CHIRALITY, BICYCLOHEPTANE P, CHAMPHANE

CLC Number:

O621

Cite this article

YANG DENGGUI;HUNG SHUN-MING;CHEN CHIN-ZON;JIANG YUEZHONG;MI AIQIAO. A new chiral β-sulfiny dienophile for asymmetric diels-alder reaction[J]. Chin. J. Org. Chem., 1993, 13(2): 183-185.

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新的手性β-亚磺酰亲双烯体用于不对称Diels-Alder反应

A new chiral β-sulfiny dienophile for asymmetric diels-alder reaction

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