Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (2): 162-165. Previous Articles     Next Articles

Original Articles

(Z)-1-[2-(二苯基碘化锡基)乙烯基]-1-环己醇的合成、晶体结构和性质

朱东升;戴慧聪;单希林;田来进;傅芳信;潘华德;邢彦;林永华   

  1. 东北师范大学化学系;中国科学院长春应用化学研究所;黑龙江省安达市大庆石油学院化工系
  • 发布日期:1998-04-25

Synthesis, crystal structure and properties of (Z)-1-[2- (bisphenyl-iodine-stannyl)vinyl]-1-cyclohexanol

ZHU DONGSHENG;DAI HUICONG;SHAN XILIN;TIAN LAIJIN;FU FANGXIN;PAN HUADE;XING YAN;LIN YONGHUA   

  • Published:1998-04-25

Synthesis, crystal structure and properties of title molecular are discribed. This crystal is monoclinic, belonging to space group P2~1 with a=0.9255(3)nm, b=1.0504(3)nm, c=1.0217(3)nm, β=100.99(2)°, V=0.9750nm^3, Z=2, D~c=1.790g/cm^3, R=0.025. The structure was solved by direct method. The tin atom of the title molecule exists in a distorted-trigonal-bipyramidal geometry, defined by three carbon, one iodine and one oxygen atoms leading to a five-membered chelate ring. The X-ray analysis show that the title compound has the properties of substitution reaction with halogen rather than addition reaction.

Key words: HYDROCARBON WITH TWO PHENYLS, ORGANIC SYNTHESIS, ORGANO TIN COMPOUNDS, ANTINEOPLASTIC ACTIVITY, VINYL COMPOUNDS, CYCLOHEXANOL P, CRYSTAL STRUCTURE

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