Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (12): 1508-1529. Previous Articles     Next Articles




  1. (中国科学技术大学化学系 合肥 230026)
  • 收稿日期:2004-05-10 修回日期:2005-04-20 发布日期:2005-11-30
  • 通讯作者: 郭庆祥

Ni-catalyzed C(sp2)-carbon and C(sp2)-heteroatom Cross-coupling Reactions

LI Zhe, FU Yao, LIU Lei, GUO Qing-Xiang*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • Received:2004-05-10 Revised:2005-04-20 Published:2005-11-30
  • Contact: GUO Qing-Xiang

Nickel-catalyzed C—C and C-heteroatom cross-coupling reactions are reviewed. The reactions include Heck reaction, Sonogashira reaction, Kumada-Corriu reaction, Negishi reaction, Stille reaction, Suzuki reaction, Ullmann reaction, C—N coupling, C—O coupling, C—P coupling, and C—S coupling. The substrates, reaction conditions, selectivities and yields of these reactions are described. The mechanistic studies on Ni-catalyzed reactions were also surveyed.

Key words: cross-coupling, catalytic reaction, Ni, reaction mechanism