Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (01): 137-140. Previous Articles     Next Articles

Reports

手性方酰化哒嗪衍生物的合成及荧光特性研究

熊俊如*,陈稼轩,向清祥,张元勤   

  1. (乐山师范学院化学与生命科学系 乐山 614004)
  • 收稿日期:2007-02-22 修回日期:1900-01-01 发布日期:2008-01-23
  • 通讯作者: 熊俊如

Synthesis and Fluorescence of Chiral Pyridazine Derivatives ofSquaric Acid

XIONG Jun-Ru*, CHEN Jia-Xuan, XIANG Qing-Xiang, ZHANG Yuan-Qin   

  1. (Department of Chemistry and Life Science, Leshan Teachers College, Leshan 614004)
  • Received:2007-02-22 Revised:1900-01-01 Published:2008-01-23
  • Contact: XIONG Jun-Ru

The new chiral N,N'-bis(squaryl)-3,6-pyridazinrlene bis(methylamine) has been synthesized by the reaction 3,6-diformylpyridazine with methyl lactamate, o-aminophenol and squaric acid. The structures of the new compound and its intermediates were confirmed by IR, 1H NMR spectra and elemental analysis. The effect of metal ions on the fluorescence characteristics of the compound was also investigated. The selective interaction between metal ions (Cu2+, Ni2+) and the compound led to obvious fluorescence quenching.

Key words: pyridazine derivative, chiral methyl N-squaryl lactamate, synthesis, ion recognition, fluorescence quenching, fluorescence