化学学报 ›› 1983, Vol. 41 ›› Issue (9): 809-816. 上一篇    下一篇

研究论文

化学修饰电极的研究 V:铁卟啉修饰电极对氧的催化还原

董绍俊;许莉娟;马跃   

  1. 中国科学院长春应用化学研究所
  • 发布日期:1983-09-15

Researches on chemically modified electrode V: Catalytic reduction of oxygen on iron porphyrin modified electrode

DONG SHAOJUN;XU LIJUAN;MA YUE   

  • Published:1983-09-15

关键词: 卟吩 P, 氧, 铁化合物, 化学修饰电极, 电催化

By surface organio synthesis a Fe (III) tetra-o-aminophenyl porphyrin modified electrode was successfully prepared on glassy carbon electrode surface through amidization. The preparation considitions were invesigated in detail. Using cyclie voltametry and cyclie semidifferential polarography in an acidic aqueous solution the behavior of the catalytic reduction of oxygen on iron porphyrin modified electrode was studied. Based on experimental results it was shown that the irreversible process of 2- electronreduction to hydrogen peroxide belongs to EC parallel catalytic process.

Key words: PORPHINE P, OXYGEN, IRON COMPOUNDS, CHEMICAL MODIFIED ELECTRODE, ELECTRO-CATALYSIS

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