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化学学报
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化学学报 ›› 1988, Vol. 46 ›› Issue (4): 360-363. 上一篇    下一篇

研究论文

某些Au(III)、Au(I)配离子在溶液中扩散的研究

陈景仁;邱陵;安可珍   

  1. 兰州大学现代物理系
  • 发布日期:1988-04-15

Study on the diffusion of some Au(III) and Au(I) complexes in solution

CHEN JINGREN;QIU LING;AN KEZHEN   

  • Published:1988-04-15

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611

被引次数

1

用毛细管色谱在25℃测定了AuCl4、[Au(SO3)2]、[Au(CSN2H4)2]、[Au(CN)2]等配位体离子在HCl溶液中的扩散系数及AuCl4阴离子的扩散活化能, 并与文献中其它配阴离子的D值比较, 认为扩散离子的质量和所载电荷可能是决定配阴离子扩散系数的主要因素.

关键词: 金, 毛细管色谱, 盐酸, 扩散系数, 金络合物, 高氯酸盐, 离子浓度, 溶液化学, 溶液理论

The diffusion coefficients of some of the Au(III), Au(I)-complexes and the diffusion activation energy of AuCl4- in HCl solution have been determine at 25癈 by capillary method. Analyzing the results obtained in combination with other published data, authors suggest that both the charge no. and mass of anionic metal-complexes may be the prime factors determing the magnitude of diffusion coefficient

Key words: GOLD, CAPILLARY CHROMATOGRAPHY, HYDROCHLORIC ACID, DIFFUSION COEFFICIENTS, GOLD COMPLEX, PERCHLORATE, ION CONCENTRATION, SOLUTION CHEMISTRY, SOLUTION THEORY

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