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化学学报
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化学学报 ›› 1994, Vol. 52 ›› Issue (2): 199-203. 上一篇    下一篇

研究论文

N,N'-双(2-羟基-3-甲氧基-5-甲基苯甲叉基)乙二胺合钴(Ⅱ) 类似物的合成及其对氧分子的加合性能

赵存祥;马建标;何炳林   

  1. 南开大学高分子化学研究所
  • 发布日期:1994-02-15

The synthesis and dioxygen affinity of N,N'-ethylene bis(2-hydroxy- 3-methoxy-5-methylphenylmethylideneiminato) cobalt(Ⅱ) and its analogues

ZHAO CUNXIANG;MA JIANBIAO;HE BINGLIN   

  • Published:1994-02-15

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被引次数

17 | 2

2-羟基-3-甲氧基-5-甲基苯甲醛分别与乙二胺,1,2-丙二胺,1,3-丙二胺,2,3-二甲基-2,3-丁二胺及邻苯二胺反应, 合成出一系列二元Schiff 碱型化合物. 测定Schiff碱与钴(Ⅱ)离子配合后的配合物对氧分子的加合常数, 讨论了结构与加合性能之间的关系,配合物中二胺-钴螯合环的刚性对配合物的氧加合性有重要影响

关键词: 苯甲醛 P, 氧, 钴络合物, 席夫碱, 丙二胺, 二胺, 苯二胺, 乙二胺 P, 丁二胺, 加合性

Five binary Schiff bases and their dioxygen affinity Co(II) complexes were synthesized from 2-hydroxy-3-methoxy-5-methylbenzaldehyde and diamines such as ethylenediamine, 1,2-propylenediamine, 2,3-dimethyl-2, 3-butylenediamine, 1,3-propylenediamine and 1,2-phenylenediamine. The adduction constants of these complexes to dioxygen (O2) were measured in diglyme solution with 4-methylpyridine as an axial ligand. Their affinity to O2 was influenced remarkably by rigidity of the diamine-Co(II) chelating ring in the complexes.

Key words: BENZALDEHYDE P, OXYGEN, COBALT COMPLEX, SCHIFF BASE, PROPANEDIAMINE, DIAMINE, BENZENEDIAMINE, ETHANEDIAMINE P, BUTANEDIAMINE

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