有机化合物极谱催化波研究的进展

摘要/Abstract

评述有机化合物极谱催化波研究的进展.建议有机化合物极谱催化波的主要类型及其命名分别为:(1)平行催化波,包括平行催化波、诱导吸附-平行催化波和缔合-平行催化波;(2)平行催化氢波,包括平行催化氢波和缔合-平行催化氢波.简要介绍蛋白质、黄酮类化合物、甾族类化合物、醌类化合物、α,β-不饱和羰基化合物、含氮化合物和荷电表面活性剂等不同种类有机化合物的极谱催化波及其应用.

关键词: 有机化合物, 极谱催化波, 自由基, 氧化剂, 电分析化学

The advances in polarographic catalytic wave of organic compound in the presence of oxidant are reviewed with 62 references. The classification and name of the catalytic wave are proposed as follows: (1) the parallel catalytic wave, which includes the parallel catalytic wave, the induced adsorption parallel catalytic wave and the association-parallel catalytic wave. (2) the parallel catalytic hydrogen wave, which includes the parallel catalytic hydrogen wave and the association -parallel catalytic hydrogen wave. The polarographic catalytic waves of organic compounds, such as protein, flavone, steroide, quinone, α,β-unsaturated carbonyl compound, nitrogen containing substances and charged surfactants, and their application are briefly introduced.

Key words: organic compound, polarographic catalytic wave, free radical, oxidant, electrochemical analysis

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过玮, 何平, 宋俊峰. 有机化合物极谱催化波研究的进展[J]. 化学学报, 2004, 62(10): 929-934.

GUO Wei, HE Ping, SONG Jun-Feng. Progress in the Study on the Polarographic Catalytic Wave of Organic Compound[J]. Acta Chimica Sinica, 2004, 62(10): 929-934.

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