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化学学报
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化学学报 ›› 2008, Vol. 66 ›› Issue (12): 1460-1464. 上一篇    下一篇

研究论文

高色纯度的红色掺杂型电致发光材料的合成及其性能研究

皮雅娟a 汤 昊b 赵国生c 孙润光b 朱为宏*,a   

  1. (a华东理工大学结构可控先进功能材料及其制备教育部重点实验室 精细化工研究所 上海 200237)
    (b上海大学材料科学与工程学院 上海 201800)
    (c浙江闰土股份有限公司 上虞 312368)
  • 投稿日期:2007-11-13 修回日期:2008-01-17 发布日期:2008-06-28
  • 通讯作者: 朱为宏

Synthesis and Electroluminescent Properties of Red Dopant with High Color Purity

PI, Ya-Juan a TANG, Hao b ZHAO, Guo-Sheng c SUN, Run-Guang b ZHU, Wei-Hong * ,a   

  1. (a Key Laboratory for Advanced Materials, Ministry of Education, Institute of Fine Chemicals,
    East China University of Science & Technology, Shanghai 200237)
    (b School of Materials Science and Engineering, Shanghai University, Shanghai 201800)
    (c Zhejiang Runtu Co. Ltd., Shangyu 312368)
  • Received:2007-11-13 Revised:2008-01-17 Published:2008-06-28
  • Contact: ZHU, Wei-Hong

PDF

631

被引次数

10 | 2

以吡喃腈作为电子受体、吲哚啉作为电子给体单元, 合成了一种吲哚啉衍生物DADIN作为高色纯度的红色掺杂型电致发光材料, 并对其溶液特性和有机电致发光器件性能进行了研究. 相对于柯达公司经典掺杂型红色发光材料DCJTB, 该发光材料的合成简单、提纯工艺易行、产率高, 并具有更纯正的红色发光. 研究表明, 以DADIN作为掺杂型电致发光材料的有机电致发光器件的电流效率是DCJTB的1.5倍, 实为DCJTB理想的替代品.

关键词: 高色纯度, 红光, 电致发光材料, 合成, 性能

A red electroluminescent material DADIN with a high color purity was prepared from 4-(dicyanomethylene)-2,6-dimethyl-4H-pyran as its electron-acceptor and indoline unit as its electron-donor. With respect to the Kodak’s traditional red dopant of DCJTB, it was proved that the synthesis and purification procedures of DADIN were simple, and the yield was high. In addition, the electroluminescent device based on DADIN as doping emitter has 1.5 times of current efficiency as DCJTB with high color saturation, indicative of a promising red emitting alternate to DCJTB.

Key words: high color purity, red light, electroluminescent material, synthesis, property