通过赝反伽伐尼反应实现金纳米粒子模块替换

doi:10.6023/A20040134

化学学报 ›› 2020, Vol. 78 ›› Issue (5): 407-411.DOI: 10.6023/A20040134 上一篇下一篇

研究通讯

通过赝反伽伐尼反应实现金纳米粒子模块替换

金凤鸣^a,b,c, 董宏伟^a,b,c, 赵燕^a,b,c, 庄胜利^a,c, 廖玲文^a,c, 闫楠^a,c, 古万苗^a,b,c, 查珺^a,b,c, 袁金云^d, 李进^e, 邓海腾^f, 甘自保^a,c, 杨金龙^d, 伍志鲲^a,c

a 中国科学院固体物理研究所中国科学院材料物理重点实验室安徽省纳米材料与技术重点实验室中国科学院纳米卓越中心合肥 230031;
b 中国科学技术大学合肥 230026;
c 安徽大学物质科学与信息技术研究院合肥 230601;
d 中国科学技术大学合肥微尺度物质科学国家研究中心合肥 230026;
e 清华大学生命科学学院清华大学-北京大学生命科学联合中心北京 100084;
f 清华大学生命科学学院生物信息学教育部重点实验室北京 100084

投稿日期:2020-04-30 发布日期:2020-05-07
通讯作者: 甘自保, 伍志鲲 E-mail:zbgan@iim.ac.cn;zkwu@issp.ac.cn
基金资助:
项目受国家自然科学基金（Nos.21925303，21971246，21829501，21905284，21771186，21603234，21222301，21171170，21528303）、中国博士后科学基金会（Y94G4E356B）、中国科学院合肥研究院院长基金（BJPY2019A02）、中科院合肥物质科学研究院“十三五”规划重点支持项目（KP-2017-16）、中国科学院/国家外国专家局创新团队国际合作伙伴计划和合肥物质科学技术中心方向项目培育基金（2017FXCX002）资助.

Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process

Jin Fengming^a,b,c, Dong Hongwei^a,b,c, Zhao Yan^a,b,c, Zhuang Shengli^a,c, Liao Lingwen^a,c, Yan Nan^a,c, Gu Wanmiao^a,b,c, Zha Jun^a,b,c, Yuan Jinyun^d, Li Jin^e, Deng Haiteng^f, Gan Zibao^a,c, Yang Jinlong^d, Wu Zhikun^a,c

a Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;
b University of Science and Technology of China, Hefei 230026, China;
c Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;
d Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China;
e Tsinghua University-Peking University Joint Center for Life Sciences, School of Life Sciences, Tsinghua University, Beijing 100084, China;
f MOE Key Laboratory of Bioinformatics, School of Life Sciences, Tsinghua University, Beijing 100084, China

Received:2020-04-30 Published:2020-05-07
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21925303, 21971246, 21829501, 21905284, 21771186, 21603234, 21222301, 21171170, 21528303), China Postdoctoral Science Foundation (Y94G4E356B), CASHIPS Director's Fund (BJPY2019A02), Key Program of 13th five-year plan, CASHIPS (KP-2017-16), CAS/SAFEA International Partnership Program for Creative Research Teams and Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology (2017FXCX002).

文章分享

1. Supporting_Information-A20040134.pdf(1032KB)

摘要/Abstract

通过可控的方式精确调控纳米粒子的结构仍是一个富有挑战性和鼓舞人心的课题.尽管单原子或两、三个金属原子的精细调控已经在金纳米粒子中实现，涉及三个以上金属原子的取代（模块取代）还没有报道.本工作报道了环己硫醇配体保护的Au₄₈（CHT）₂₆的合成及其通过赝反伽伐尼过程的模块取代.单晶结构揭示模块取代的产物与母体团簇共用一个相似的Au₃₁（CHT）₁₂主体，但剩余部分不同（Au₆（CHT）₁₁ vs.Au₁₆（CHT）₁₄）.一个有趣的发现是模块取代抑制了Au₄₈（CHT）₂₆的光热过程，却增强了它的发射，赋予了所合成团簇更好的双（多）功能应用潜力.光热效应的减弱和发射的增强也暗示了这两种作用能够彼此至少部分转化，对于研究这两种效应之间的相互影响也具有重要的启示.

关键词: 金纳米团簇, 模块替换, 赝反伽伐尼反应, 光热效应, 荧光

Precisely modulating the structure of nanoparticles in a controlled manner is still a challenging and inspiring topic. Although the single or few-metal atom tailoring of gold nanoparticles has been reported, local structural replacement involving over three net metal atoms (module replacement, MR) has not been hitherto achieved. Herein, we report the synthesis of cyclohexanethiolated metal nanoclusters (NCs) Au₄₈(CHT)₂₆ and their MR by a so-called pseudo-anti-galvanic reaction (AGR) process. The MR product Au₃₇(CHT)₂₃ shares a similar Au₃₁(CHT)₁₂ unit with its predecessor Au₄₈(CHT)₂₆; however, it differs from its predecessor in the remaining section (Au₆(CHT)₁₁ vs. Au₁₆(CHT)₁₄), as revealed by single-crystal X-ray crystallography (SCXC). Interestingly, the MR inhibits the photothermy but enhances the emission of Au₄₈(CHT)₂₆ NCs, which might endow the as-obtained NC better potential for bi(multiple)-functional application. The counter effects of the MR on the emission and photothermy indicate that photoluminescence and photothermy can be at least partly converted into each other, which has some important implications for the understanding of their interaction.

Key words: gold nanoparticles, module replacement, pseudo-anti-galvanic reaction (AGR), photothermy, photoluminescence

引用此文

金凤鸣, 董宏伟, 赵燕, 庄胜利, 廖玲文, 闫楠, 古万苗, 查珺, 袁金云, 李进, 邓海腾, 甘自保, 杨金龙, 伍志鲲. 通过赝反伽伐尼反应实现金纳米粒子模块替换[J]. 化学学报, 2020, 78(5): 407-411.

Jin Fengming, Dong Hongwei, Zhao Yan, Zhuang Shengli, Liao Lingwen, Yan Nan, Gu Wanmiao, Zha Jun, Yuan Jinyun, Li Jin, Deng Haiteng, Gan Zibao, Yang Jinlong, Wu Zhikun. Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process[J]. Acta Chimica Sinica, 2020, 78(5): 407-411.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430.
[2] Negishi, Y.; Chaki, N. K.; Shichibu, Y.; Whetten, R. L.; Tsukuda, T. J. Am. Chem. Soc. 2007, 129, 11322.
[3] Sánchez-Castillo, A.; Noguez, C.; Garzón, I. L. J. Am. Chem. Soc. 2010, 132, 1504.
[4] Parker, J. F.; Fields-Zinna, C. A.; Murray, R. W. Acc. Chem. Res. 2010, 43, 1289.
[5] Desireddy, A.; Conn, B. E.; Guo, J.; Yoon, B.; Barnett, R. N.; Monahan, B. M.; Kirschbaum, K.; Griffith, W. P.; Whetten, R. L.; Landman, U.; Bigioni, T. P. Nature 2013, 501, 399.
[6] Yamazoe, S.; Koyasu, K.; Tsukuda, T. Acc. Chem. Res. 2014, 47, 816.
[7] Mathew, A.; Pradeep, T. Part. Part. Syst. Charact. 2014, 31, 1017.
[8] Alhilaly, M. J.; Bootharaju, M. S.; Joshi, C. P.; Besong, T. M.; Emwas, A. H.; Juarez-Mosqueda, R.; Kaappa, S.; Malola, S.; Adil, K.; Shkurenko, A.; Hakkinen, H.; Eddaoudi, M.; Bakr, O. M. J. Am. Chem. Soc. 2016, 138, 14727.
[9] Zhao, Y.; Zhuang, S.; Liao, L.; Wang, C.; Xia, N.; Gan, Z.; Gu, W.; Li, J.; Deng, H.; Wu, Z. J. Am. Chem. Soc. 2020, 142, 973.
[10] Zhu, M.; Li, M.; Yao, C.; Xia, N.; Zhao, Y.; Yan, N.; Liao, L.; Wu, Z. Acta Phys.-Chim. Sin. 2018, 34, 792.
[11] Qian, H.; Zhu, Y.; Jin, R. ACS Nano 2009, 3, 3795.
[12] Jin, R.; Qian, H.; Wu, Z.; Zhu, Y.; Zhu, M.; Mohanty, A.; Garg, N. J. Phys. Chem. Lett. 2010, 1, 2903.
[13] Wu, Z.; MacDonald, M. A.; Chen, J.; Zhang, P.; Jin, R. J. Am. Chem. Soc. 2011, 133, 9670.
[14] Knoppe, S.; Boudon, J.; Dolamic, I.; Dass, A.; Bürgi, T. Anal. Chem. 2011, 83, 5056.
[15] Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. J. Am. Chem. Soc. 2010, 132, 8280.
[16] Yang, H.; Wang, Y.; Huang, H.; Gell, L.; Lehtovaara, L.; Malola, S.; Häkkinen, H.; Zheng, N. Nat. Commun. 2013, 4, 2422.
[17] Chen, J.; Zhang, Q. F.; Williard, P. G.; Wang, L. S. Inorg. Chem. 2014, 53, 3932.
[18] Tian, S.; Li, Y.-Z.; Li, M.-B.; Yuan, J.; Yang, J.; Wu, Z.; Jin, R. Nat. Commun. 2015, 6, 8667.
[19] Dass, A.; Theivendran, S.; Nimmala, P. R.; Kumara, C.; Jupally, V. R.; Fortunelli, A.; Sementa, L.; Barcaro, G.; Zuo, X.; Noll, B. C. J. Am. Chem. Soc. 2015, 137, 4610.
[20] Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2016, 138, 8710.
[21] Wan, X.-K.; Cheng, X.-L.; Tang, Q.; Han, Y.-Z.; Hu, G.; Jiang, D. E.; Wang, Q.-M. J. Am. Chem. Soc. 2017, 139, 9451.
[22] Zhang, S.-S.; Feng, L.; Senanayake, R. D.; Aikens, C. M.; Wang, X.-P.; Zhao, Q.-Q.; Tung, C.-H.; Sun, D. Chem. Sci. 2018, 9, 1251.
[23] Chen, S.; Ingram, R. S.; Hostetler, M. J.; Pietron, J. J.; Murray, R. W.; Schaaff, T. G.; Khoury, J. T.; Alvarez, M. M.; Whetten, R. L. Science 1998, 280, 2098.
[24] Tsunoyama, H.; Ichikuni, N.; Sakurai, H.; Tsukuda, T. J. Am. Chem. Soc. 2009, 131, 7086.
[25] Gao, Y.; Shao, N.; Pei, Y.; Zeng, X. C. Nano Lett. 2010, 10, 1055.
[26] Luo, Z.; Zheng, K.; Xie, J. Chem. Commun. 2014, 50, 5143.
[27] Azubel, M.; Koivisto, J.; Malola, S.; Bushnell, D.; Hura, G. L.; Koh, A. L.; Tsunoyama, H.; Tsukuda, T.; Pettersson, M.; Häkkinen, H.; Kornberg, R. D. Science 2014, 345, 909.
[28] Li, M.; Tian, S.; Wu, Z. Chin. J. Chem. 2017, 35, 567.
[29] Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2014, 136, 11922.
[30] Song, Y.; Abroshan, H.; Chai, J.; Kang, X.; Kim, H.; Zhu, M.; Jin, R. Chem. Mater. 2017, 29, 3055.
[31] Yao, C.; Tian, S.; Liao, L.; Liu, X.; Xia, N.; Yan, N.; Gan, Z.; Wu, Z. Nanoscale 2015, 7, 16200.
[32] Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 10011.
[33] Xia, N.; Gan, Z.; Liao, L.; Zhuang, S.; Wu, Z. Chem. Commun. 2017, 53, 11646.
[34] Dainese, T.; Antonello, S.; Bogialli, S.; Fei, W.; Venzo, A.; Maran, F. ACS Nano 2018, 12, 7057.
[35] Li, Q.; Luo, T.; Taylor, M. G.; Wang, S.; Zhu, X.; Song, Y.; Mpourmpakis, G.; Rosi, N. L.; Jin, R. Sci. Adv. 2017, 3, e1603193.
[36] Wu, Z. Acta Phys.-Chim. Sin. 2017, 33, 1930(in Chinese). (伍志鲲, 物理化学学报, 2017, 33, 1930.)
[37] Wu, Z. Angew. Chem. Int. Ed. 2012, 51, 2934.
[38] Tian, S.; Yao, C.; Liao, L.; Xia, N.; Wu, Z. Chem. Commun. 2015, 51, 11773.
[39] Gan, Z.; Xia, N.; Wu, Z. Acc. Chem. Res. 2018, 51, 2774.
[40] Yao, C.; Lin, Y.; Yuan, J.; Liao, L.; Zhu, M.; Weng, L.; Yang, J.; Wu, Z. J. Am. Chem. Soc. 2015, 137, 15350.
[41] Yao, C.; Lin, Y.; Yuan, J.; Liao, L.; Zhu, M.; Weng, L.; Yang, J.; Wu, Z. J. Am. Chem. Soc. 2015, 137, 15350.
[42] Liao, L.; Zhou, S.; Dai, Y.; Liu, L.; Yao, C.; Fu, C.; Yang, J.; Wu, Z. J. Am. Chem. Soc. 2015, 137, 9511.
[43] Zhu, M.; Wang, P.; Yan, N.; Qi, C.; He, L.; Zhao, Y.; Xia, N.; Yao, C.; Li, J.; Deng, H.; Zhu, Y.; Pei, Y.; Wu, Z. Angew. Chem. Int. Ed. 2018, 57, 4500.
[44] Zhang, W.; Zhuang, S.; Liao, L.; Dong, H.; Xia, N.; Li, J.; Deng, H.; Wu, Z. Inorg. Chem. 2019, 58, 5388.
[45] Gan, Z.; Chen, J.; Liao, L.; Zhang, H.; Wu, Z. J. Phys. Chem. Lett. 2018, 9, 204.
[46] Das, A.; Liu, C.; Byun, H. Y.; Nobusada, K.; Zhao, S.; Rosi, N.; Jin, R. Angew. Chem. Int. Ed. 2015, 54, 3140.
[47] Das, A.; Li, T.; Nobusada, K.; Zeng, C.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2013, 135, 18264.
[48] Chen, Y.; Liu, C.; Tang, Q.; Zeng, C.; Higaki, T.; Das, A.; Jiang, D. E.; Rosi, N. L.; Jin, R. J. Am. Chem. Soc. 2016, 138, 1482.
[49] Dong, H.; Liao, L.; Zhuang, S.; Yao, C.; Chen, J.; Tian, S.; Zhu, M.; Liu, X.; Li, L.; Wu, Z. Nanoscale 2017, 9, 3742.
[50] Dong, H.; Liao, L.; Wu, Z. J. Phys. Chem. Lett. 2017, 8, 5338.
[51] Zhuang, S.; Liao, L.; Yuan, J.; Wang, C.; Zhao, Y.; Xia, N.; Gan, Z.; Gu, W.; Li, J.; Deng, H.; Yang, J.; Wu, Z. Angew. Chem. Int. Ed. 2018, 57, 15450.
[52] Liao, L.; Zhuang, S.; Wang, P.; Xu, Y.; Yan, N.; Dong, H.; Wang, C.; Zhao, Y.; Xia, N.; Li, J.; Deng, H.; Pei, Y.; Tian, S. K.; Wu, Z. Angew. Chem. Int. Ed. 2017, 56, 12644.
[53] Wu, Z.; Jin, R. Nano Lett. 2010, 10, 2568.
[54] Yu, Y.; Luo, Z.; Chevrier, D. M.; Leong, D. T.; Zhang, P.; Jiang, D. E.; Xie, J. J. Am. Chem. Soc. 2014, 136, 1246.
[55] Wang, S.; Zhu, X.; Cao, T.; Zhu, M. Nanoscale 2014, 6, 5777.
[56] Pyo, K.; Thanthirige, V. D.; Kwak, K.; Pandurangan, P.; Ramakrishna, G.; Lee, D. J. Am. Chem. Soc. 2015, 137, 8244.
[57] Gan, Z.; Lin, Y.; Luo, L.; Han, G.; Liu, W.; Liu, Z.; Yao, C.; Weng, L.; Liao, L.; Chen, J.; Liu, X.; Luo, Y.; Wang, C.; Wei, S.; Wu, Z. Angew. Chem. Int. Ed. 2016, 55, 11567.
[58] Goswami, N.; Yao, Q.; Luo, Z.; Li, J.; Chen, T.; Xie, J. J. Phys. Chem. Lett. 2016, 7, 962.
[59] Sugiuchi, M.; Maeba, J.; Okubo, N.; Iwamura, M.; Nozaki, K.; Konishi, K. J. Am. Chem. Soc. 2017, 139, 17731.
[60] Gan, Z.; Chen, J.; Wang, J.; Wang, C.; Li, M. B.; Yao, C.; Zhuang, S.; Xu, A.; Li, L.; Wu, Z. Nat. Commun. 2017, 8, 14739.
[61] Zhuang, S.; Liao, L.; Yuan, J.; Xia, N.; Zhao, Y.; Wang, C.; Gan, Z.; Yan, N.; He, L.; Li, J.; Deng, H.; Guan, Z.; Yang, J.; Wu, Z. Angew. Chem. Int. Ed. 2019, 58, 4510.
[62] Wang, P. Environ. Sci.:Nano 2018, 5, 1078.
[63] Jin, Y.; Chang, J.; Shi, Y.; Shi, L.; Hong, S.; Wang, P. J. Mater. Chem. A 2018, 6, 7942.
[64] Huang, X.; El-Sayed, I. H.; Qian, W.; El-Sayed, M. A. J. Am. Chem. Soc. 2006, 128, 2115.
[65] Huang, X.; Jain, P. K.; El-Sayed, I. H.; El-Sayed, M. A. Lasers Med. Sci. 2008, 23, 217.
[66] Chen, J.; Glaus, C.; Laforest, R.; Zhang, Q.; Yang, M.; Gidding, M.; Welch, M. J.; Xia, Y. Small 2010, 6, 811.
[67] Tang, S.; Huang, X.; Zheng, N. Chem. Commun. 2011, 47, 3948.
[68] Tang, S.; Chen, M.; Zheng, N. Nano Res. 2014, 8, 165.
[69] Abadeer, N. S.; Murphy, C. J. J. Phys. Chem. C 2016, 120, 4691.
[70] Liu, Y.; Yang, Z.; Huang, X.; Yu, G.; Wang, S.; Zhou, Z.; Shen, Z.; Fan, W.; Liu, Y.; Davisson, M.; Kalish, H.; Niu, G.; Nie, Z.; Chen, X. ACS Nano 2018, 12, 8129.
[71] Lu, B.; Chen, Y.; Li, P.; Wang, B.; Mullen, K.; Yin, M. Nat. Commun. 2019, 10, 767.

通过赝反伽伐尼反应实现金纳米粒子模块替换

Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process

PDF

补充材料

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价

[1]	葛凤洁, 张开志, 曹清鹏, 徐慧, 周涛, 张文浩, 班鑫鑫, 张晓波, 李娜, 朱鹏. 柔性芴基嵌段型延迟荧光二聚体的设计、合成及电致发光性能[J]. 化学学报, 2023, 81(9): 1157-1166.
[2]	王一诺, 邵世洋, 王利祥. 窄谱带多重共振有机高分子荧光材料研究进展^★[J]. 化学学报, 2023, 81(9): 1202-1214.
[3]	车飞达, 赵晓茗, 张馨, 丁琪, 王昕, 李平, 唐波. 抑郁症相关活性分子的荧光成像^★[J]. 化学学报, 2023, 81(9): 1255-1264.
[4]	王晓, 王星文, 肖乐辉. 单分子荧光成像研究单颗粒纳米催化机制[J]. 化学学报, 2023, 81(8): 1002-1014.
[5]	武虹乐, 郭锐, 迟涵文, 唐永和, 宋思睿, 葛恩香, 林伟英. 喹啉基粘度荧光探针的合成及其检测应用[J]. 化学学报, 2023, 81(8): 905-911.
[6]	郑文山, 高冠斌, 邓浩, 孙涛垒. Ag₂Se@Ag₂S核壳量子点的室温合成及其近红外荧光性能优化[J]. 化学学报, 2023, 81(7): 763-770.
[7]	刘振宇, 饶俊峰, 祝守加, 王兵洋, 余帆, 冯全友, 解令海. 溶液加工型自主体热活化延迟荧光材料的研究进展[J]. 化学学报, 2023, 81(7): 820-835.
[8]	孙博, 琚雯雯, 王涛, 孙晓军, 赵婷, 卢晓梅, 陆峰, 范曲立. 高分散共轭聚合物-金属有机框架纳米立方体的制备及抗肿瘤应用[J]. 化学学报, 2023, 81(7): 757-762.
[9]	王银凤, 李猛, 陈传峰. 基于手性三蝶烯的红光热激活延迟荧光聚合物及其有机发光二极管研究^★[J]. 化学学报, 2023, 81(6): 588-594.
[10]	梁攀, 张宏淑, 黄宏升, 李飒英, 张笑恬, 王英, 李连庆, 刘志宏. 一种高效窄带蓝色荧光粉Ba₃Y₂B₆O₁₅:Bi³⁺及其应用研究[J]. 化学学报, 2023, 81(4): 371-380.
[11]	吕鑫, 吴仪, 张勃然, 郭炜. 过氧化氢激活型近红外氟硼二吡咯光敏剂的设计、合成及光动力治疗研究[J]. 化学学报, 2023, 81(4): 359-370.
[12]	张少秦, 李美清, 周中军, 曲泽星. 多共振热激活延迟荧光过程的理论研究[J]. 化学学报, 2023, 81(2): 124-130.
[13]	贾彦荣, 徐凯, 赵彦英, 倪华钢, 吴滢, 夏敏. 推拉电子基团区域异构苯并咪唑的发射行为与力致荧光变色性能研究[J]. 化学学报, 2023, 81(12): 1716-1723.
[14]	黄艳琴, 栗丽君, 杨书培, 张瑞, 刘兴奋, 范曲立, 黄维. HA-AuNPs/FDF用于透明质酸酶的高灵敏检测、肿瘤靶向细胞荧光成像和光疗[J]. 化学学报, 2023, 81(12): 1687-1694.
[15]	贺晓梦, 袁方, 张素雅, 张健健. 基于尼罗红类ONOO^–近红外荧光探针的开发及其成像应用[J]. 化学学报, 2023, 81(11): 1515-1521.