太阳能光催化分解水制氢※

doi:10.6023/A21120607

化学学报 ›› 2022, Vol. 80 ›› Issue (6): 827-838.DOI: 10.6023/A21120607 上一篇下一篇

所属专题：中国科学院青年创新促进会合辑

综述

太阳能光催化分解水制氢^※

祁育, 章福祥^*()

中国科学院大连化学物理研究所催化基础国家重点实验室辽宁大连 116023

投稿日期:2021-12-30 发布日期:2022-07-07
通讯作者: 章福祥

作者简介:

祁育, 副研究员, 硕导, 2012年本科毕业于吉林大学, 随后加入中国科学院大连化学物理研究所, 在李灿院士和章福祥研究员指导下获得博士学位. 2018年1月加入章福祥课题组, 主要研究方向为光催化Z机制全分解水制氢研究.

章福祥, 研究员, 博导, 国家杰出青年基金获得者, 英国皇家化学会会士, 入选国家百千万人才工程. 1999年获南开大学学士学位, 2004年获南开大学理学博士学位, 同年留校任教至2007年8月, 2007 年9月至2008年6月获法国CNRS博士后基金支持于巴黎第六大学做访问学者, 2008年7月至2011年9月在东京大学做博士后和特任助理教授, 2011年10月至今在中国科学院大连化学物理研究所工作. 目前主要从事宽光谱捕光催化剂全分解水制氢和太阳能光化学转化研究, 研究内容涉及宽光谱捕光光催化材料设计合成, 高效光生电荷分离体系构建以及光催化表面/界面反应机制等方面. 已在包括Nat. Commun., Nature Catal., Joule, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater.等刊物上发表SCI/EI学术论文百余篇. 担任J. Energy Chem.期刊副主编, Sci. China Chem., eScience, Renewable, NSR和化学进展等期刊编委; 可再生能源学会光化学与光催化专业委员会委员, 全国催化青年专业委员会委员, 能源与环境专业委员会委员; 正主持承担国家自然科学基金委重点项目, 国家自然科学基金杰出青年基金项目, 科技部重点专项等.

^※ 庆祝中国科学院青年创新促进会十年华诞.

基金资助:
国家自然科学基金(21902156); 国家自然科学基金(21925206)

Photocatalytic Water Splitting for Hydrogen Production^※

Yu Qi, Fuxiang Zhang()

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023

Received:2021-12-30 Published:2022-07-07
Contact: Fuxiang Zhang
About author:
^※ Dedicated to the 10th anniversary of the Youth Innovation Promotion Association, CAS.
Supported by:
National Natural Science Foundation of China(21902156); National Natural Science Foundation of China(21925206)

文章分享

摘要/Abstract

利用太阳能光催化分解水制氢是解决能源环境问题并实现太阳能有效转化和储存最有前途的技术之一, 这一“圣杯”式反应经过几十年不懈努力取得了诸多重要研究进展. 本文将综述光催化分解水制氢体系的基本概念、活性测试方法与注意事项、光催化材料种类等; 并从光催化分解水制氢的光吸收、光生电荷分离和表面催化反应等基本过程和关键科学问题的角度总结其重要研究进展, 最后对于太阳能光催化分解水制氢的挑战和潜在的发展方向进行分析和展望. 希望通过本综述的简要介绍能让刚从事光催化分解水制氢研究的青年科技人员清晰地了解掌握该领域的一些基本概念、操作规范、研究总体进展和现状等.

关键词: 氢能, 光催化, 分解水, 太阳能转化, 半导体光催化剂

Photocatalytic water splitting to produce hydrogen is one of the most promising technologies to solve energy and environmental problems and realize the effective conversion and storage of solar energy. And the development of it has attracted more and more attention with the proposed target of peaking carbon dioxide emissions before 2030 and achieving carbon neutrality before 2060. After decades of unremitting efforts, this “Holy Grail” reaction has made many important research progresses. This article will review the basic concepts, activity test methods and precautions, types of photocatalytic reactions and means of measurement for efficiency. The development of photocatalytic materials including inorganic semiconductor including oxide, (oxy)nitride, sulfur oxides, oxyhalide, sulfide and solid solutions, sensitized photocatalytic materials, polymer, metal-organic framework materials, etc. are introduced. The important research progresses from the perspective of basic processes and key scientific issues such as light absorption, photo-generated charge separation and surface catalytic reaction of photocatalytic water splitting to produce hydrogen are summarized. The strategies for improving the charge separation such as construction of heterojunction, and the reduction/oxidation cocatalyst for promoting the surface catalysis are introduced. The research progress of hydrogen production by photocatalytic overall water splitting (OWS) using one-step or two-steps photo-excitation system is also summarized in details. For the one-step system, the different materials and the strategies of realizing OWS are introduced. Moreover, for two-step system, the types of electron transfer medium, the exploration of materials and the inhibition of competing reaction are mainly discussed. Finally, the challenges and potential development directions of photocatalytic water splitting to produce hydrogen are analyzed and prospected. It is hoped that through the brief introduction of this review, young scientific and technical personnel who have just been engaged in this research will have a clear understanding of some basic concepts, operating specifications, research progresses and current status in the field of photocatalytic water splitting.

Key words: hydrogen energy, photocatalysis, water splitting, solar energy conversion, semiconductor photocatalyst

引用此文

祁育, 章福祥. 太阳能光催化分解水制氢^※[J]. 化学学报, 2022, 80(6): 827-838.

Yu Qi, Fuxiang Zhang. Photocatalytic Water Splitting for Hydrogen Production^※[J]. Acta Chimica Sinica, 2022, 80(6): 827-838.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 9

图1. 半导体光催化剂分解水制氢基本过程

Figure 1. Basic processes of water splitting to produce hydrogen over semiconductor photocatalysts

图2. 典型光催化反应装置示意图

Figure 2. Schematic diagram of a typical photocatalytic reaction device

图3. 光催化产氢/产氧半反应示意图

Figure 3. Schematic diagram of photocatalytic hydrogen/oxygen production in the presence of sacrificial reagents

图4. 顶照式光照入射光子数测量示意图

Figure 4. Schematic diagram of the measurement of the number of incident photons with top-illuminated illumination

图5. 不同厂家太阳能模拟器的光强分布图

图6. 混合阴离子光催化剂价带调控示意图

Figure 6. Schematic diagram of valence band engineering of mixed anion photocatalyst

图7. p-n结(a)和II型异质结(b)示意图

Figure 7. Schematic diagram of p-n junction (a) and type II heterojunction (b)

图8. 两步光激发法全分解水制氢的原理图

Figure 8. Schematic diagram of the two-step photoexcitation system for overall water splitting

图9. n-n型(a), p-n型(b)半导体复合结构能带弯曲示意图

Figure 9. Schematic diagram of band bending of n-n type (a), p-n type (b) semiconductor composite structure

参考文献 84

[1]	Şen, Z. Energy Combust. Sci. 2004, 30, 367. doi: 10.1016/j.pecs.2004.02.004
[2]	Momirlan, M.; Veziroglu, T. N. Int. Hydrog. Energy. 2005, 30, 795. doi: 10.1016/j.ijhydene.2004.10.011
[3]	Hisatomi, T.; Domen, K. Faraday Discuss. 2017, 198, 11. doi: 10.1039/c6fd00221h pmid: 28272623
[4]	Chen, S.; Takata, T.; Domen, K. Nat. Rev. Mater. 2017, 2, 17050. doi: 10.1038/natrevmats.2017.50
[5]	Hisatomi, T.; Domen, K. Nat. Catal. 2019, 2, 387. doi: 10.1038/s41929-019-0242-6
[6]	Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
[7]	Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/B800489G
[8]	Maeda, K.; Domen, K. J. Phys. Chem. C. 2007, 111, 7851. doi: 10.1021/jp070911w
[9]	Yang, J.; Wang, D.; Han, H.; Li, C. Acc. Chem. Res. 2013, 46, 1900. doi: 10.1021/ar300227e
[10]	Wang, Q.; Domen, K. Chem. Rev. 2020, 120, 919. doi: 10.1021/acs.chemrev.9b00201
[11]	Maeda, K. J. Photochem. Photobiol. C: Photochem. Rev. 2011, 12, 237. doi: 10.1016/j.jphotochemrev.2011.07.001
[12]	Hisatomi, T.; Minegishi, T.; Domen, K. Bull. Chem. Soc. Jpn. 2012, 85, 647. doi: 10.1246/bcsj.20120058
[13]	Hisatomi, T.; Kubota, J.; Domen, K. Chem. Soc. Rev. 2014, 43, 7520. doi: 10.1039/c3cs60378d pmid: 24413305
[14]	Qureshi, M.; Takanabe, K. Chem. Mater. 2017, 29, 158. doi: 10.1021/acs.chemmater.6b02907
[15]	Wang, Z.; Li, C.; Domen, K. Chem. Soc. Rev. 2019, 48, 2109. doi: 10.1039/C8CS00542G
[16]	Wang, Z.; Hisatomi, T.; Li, R.; Sayama, K.; Liu, G.; Domen, K.; Li, C.; Wang, L. Joule 2021, 5, 344. doi: 10.1016/j.joule.2021.01.001
[17]	Cui, J.; Li, C.; Zhang, F. ChemSusChem 2019, 12, 1872. doi: 10.1002/cssc.201801829
[18]	Chen, X.; Mao, S. S. Chem. Rev. 2007, 107, 2891. doi: 10.1021/cr0500535
[19]	Grabowska, E. Appl. Catal. B: Environ. 2016, 186, 97. doi: 10.1016/j.apcatb.2015.12.035
[20]	Ham, Y.; Hisatomi, T.; Goto, Y.; Moriya, Y.; Sakata, Y.; Yamakata, A.; Kubota, J.; Domen, K. J Mater. Chem. A 2016, 4, 3027. doi: 10.1039/C5TA04843E
[21]	Kato, H.; Kudo, A. J Phy. Chem. B 2001, 105, 4285. doi: 10.1021/jp004386b
[22]	Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125, 3082. doi: 10.1021/ja027751g
[23]	Kudo, A.; Sayama, K.; Tanaka, A.; Asakura, K.; Domen, K.; Maruya, K.; Onishi, T. J. Catal. 1989, 120, 337. doi: 10.1016/0021-9517(89)90274-1
[24]	Sato, J.; Saito, N.; Nishiyama, H.; Inoue, Y. J Phy. Chem. B 2003, 107, 7965. doi: 10.1021/jp030020y
[25]	Sato, J.; Kobayashi, H.; Inoue, Y. J Phy. Chem. B 2003, 107, 7970. doi: 10.1021/jp030021q
[26]	Sato, J.; Saito, N.; Yamada, Y.; Maeda, K.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K.; Inoue, Y. J. Am. Chem. Soc. 2005, 127, 4150. doi: 10.1021/ja042973v
[27]	Chen, S.; Zhang, F. Chin. J. Catal. 2014, 35, 1431. doi: 10.1016/S1872-2067(14)60183-2
[28]	Chen, S.; Yang, J.; Ding, C.; Li, R.; Jin, S.; Wang, D.; Han, H.; Zhang, F.; Li, C. J Mater. Chem. A 2013, 1, 5651. doi: 10.1039/c3ta10446j
[29]	Chen, S.; Qi, Y.; Liu, G.; Yang, J.; Zhang, F.; Li, C. Chem. Commun. 2014, 50, 14415. doi: 10.1039/C4CC06682K
[30]	Dong, B.; Cui, J.; Qi, Y.; Zhang, F. Adv. Mater. 2021, 33, 2004697. doi: 10.1002/adma.202004697
[31]	Fujito, H.; Kunioku, H.; Kato, D.; Suzuki, H.; Higashi, M.; Kageyama, H.; Abe, R. J. Am. Chem. Soc. 2016, 138, 2082. doi: 10.1021/jacs.5b11191
[32]	Kunioku, H.; Higashi, M.; Tomita, O.; Yabuuchi, M.; Kato, D.; Fujito, H.; Kageyama, H.; Abe, R. J. Mater. Chem. A 2018, 6, 3100. doi: 10.1039/C7TA08619A
[33]	Kudo, A.; Kato, H.; Tsuji, I. Chem. Lett. 2004, 33, 1534. doi: 10.1246/cl.2004.1534
[34]	Youngblood, W. J.; Lee, S.-H. A.; Maeda, K.; Mallouk, T. E. Acc. Chem. Res. 2009, 42, 1966. doi: 10.1021/ar9002398
[35]	Houlding, V. H.; Gratzel, M. J. Am. Chem. Soc. 1983, 105, 5695. doi: 10.1021/ja00355a032
[36]	Youngblood, W. J.; Lee, S.-H. A.; Kobayashi, Y.; Hernandez-Pagan, E. A.; Hoertz, P. G.; Moore, T. A.; Moore, A. L.; Gust, D.; Mallouk, T. E. J. Am. Chem. Soc. 2009, 131, 926. doi: 10.1021/ja809108y pmid: 19119815
[37]	Yanagida, S.; Kabumoto, A.; Mizumoto, K.; Pac, C.; Yoshino, K. J. Chem. Soc., Chem. Commun. 1985, 474.
[38]	Wang, Y.; Vogel, A.; Sachs, M.; Sprick, R. S.; Wilbraham, L.; Moniz, S. J. A.; Godin, R.; Zwijnenburg, M. A.; Durrant, J. R.; Cooper, A. I.; Tang, J. Nat. Energy 2019, 4, 746. doi: 10.1038/s41560-019-0456-5
[39]	Zhang, G.; Lan, Z.-A.; Wang, X. Angew. Chem. Int. Ed. 2016, 55, 15712. doi: 10.1002/anie.201607375
[40]	Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M. Nat. Mater. 2009, 8, 76. doi: 10.1038/nmat2317
[41]	Ma, W.; He, Y.; Liu, H. Acta Chim. Sinica 2021, 79, 914. (in Chinese) doi: 10.6023/A21030121
	(麻旺坪, 贺彦彦, 刘洪来, 化学学报, 2021, 79, 914.) doi: 10.6023/A21030121
[42]	Lin, L.; Lin, Z.; Zhang, J.; Cai, X.; Lin, W.; Yu, Z.; Wang, X. Nat. Catal. 2020, 3, 649. doi: 10.1038/s41929-020-0476-3
[43]	Lan, Z.-A.; Wu, M.; Fang, Z.; Zhang, Y.; Chen, X.; Zhang, G.; Wang, X. Angew. Chem., Int. Ed. 2022, DIO: 10. 1002/anie.202201482.
[44]	Meyer, K.; Ranocchiari, M.; van Bokhoven, J. A. Energ. Environ. Sci. 2015, 8, 1923. doi: 10.1039/C5EE00161G
[45]	Shi, Y.; Yang, A.-F.; Cao, C.-S.; Zhao, B. Coord. Chem. Rev. 2019, 390, 50. doi: 10.1016/j.ccr.2019.03.012
[46]	Guo, X.; Liu, L.; Xiao, Y.; Qi, Y.; Duan, C.; Zhang, F. Coord. Chem. Rev. 2021, 435, 213785. doi: 10.1016/j.ccr.2021.213785
[47]	Wu, Q.; Zhang, C.; Sun, K.; Jiang, H. Acta Chim. Sinica 2020, 78, 688. (in Chinese) doi: 10.6023/A20050141
	(吴浅耶, 张晨曦, 孙康, 江海龙, 化学学报, 2020, 78, 688.) doi: 10.6023/A20050141
[48]	Dhakshinamoorthy, A.; Asiri, A. M.; García, H. Angew. Chem. Int. Ed. 2016, 55, 5414. doi: 10.1002/anie.201505581 pmid: 26970539
[49]	Xu, M.; Li, D.; Sun, K.; Jiao, L.; Xie, C.; Ding, C.; Jiang, H.-L. Angew. Chem. Int. Ed. 2021, 60, 16372. doi: 10.1002/anie.202104219
[50]	Hu, H.; Wang, Z.; Cao, L.; Zeng, L.; Zhang, C.; Lin, W.; Wang, C. Nat. Chem. 2021, 13, 358. doi: 10.1038/s41557-020-00635-5
[51]	Linic, S.; Christopher, P.; Ingram, D. B. Nat. Mater. 2011, 10, 911. doi: 10.1038/nmat3151
[52]	Dong, H.; Sun, L.-D.; Yan, C.-H. Chem. Soc. Rev. 2015, 44, 1608. doi: 10.1039/c4cs00188e pmid: 25242465
[53]	Liu, G.; Niu, P.; Yin, L.; Cheng, H.-M. J. Am. Chem. Soc. 2012, 134, 9070. doi: 10.1021/ja302897b
[54]	Rahman, M. Z.; Kwong, C. W.; Davey, K.; Qiao, S. Z. Energy Environ. Sci. 2016, 9, 709. doi: 10.1039/C5EE03732H
[55]	Xu, X.; Randorn, C.; Efstathiou, P.; Irvine, J. T. S. Nat. Mater. 2012, 11, 595. doi: 10.1038/nmat3312
[56]	Maeda, K. Chem. Commun. 2013, 49, 8404. doi: 10.1039/c3cc44151b
[57]	Maeda, K.; Terashima, H.; Kase, K.; Higashi, M.; Tabata, M.; Domen, K. Bull. Chem. Soc. Jpn. 2008, 81, 927. doi: 10.1246/bcsj.81.927
[58]	Jang, J. S.; Kim, H. G.; Lee, J. S. Cataly. Today 2012, 185, 270. doi: 10.1016/j.cattod.2011.07.008
[59]	Xu, Y.; Li, A.; Yao, T.; Ma, C.; Zhang, X.; Shah, J. H.; Han, H. ChemSusChem 2017, 10, 4277. doi: 10.1002/cssc.201701598
[60]	Chen, S.; Qi, Y.; Hisatomi, T.; Ding, Q.; Asai, T.; Li, Z.; Ma, S. S. K.; Zhang, F.; Domen, K.; Li, C. Angew. Chem. Int. Ed. 2015, 54, 8498. doi: 10.1002/anie.201502686
[61]	Qi, Y.; Chen, S.; Li, M.; Ding, Q.; Li, Z.; Cui, J.; Dong, B.; Zhang, F.; Li, C. Chem. Sci. 2017, 8, 437. doi: 10.1039/C6SC02750D
[62]	Zhang, J.; Xu, Q.; Feng, Z.; Li, M.; Li, C. Angew. Chem. Int. Ed. 2008, 47, 1766. doi: 10.1002/anie.200704788 pmid: 18213667
[63]	Wang, X.; Xu, Q.; Li, M.; Shen, S.; Wang, X.; Wang, Y.; Feng, Z.; Shi, J.; Han, H.; Li, C. Angew. Chem. Int. Ed. 2012, 51, 13089. doi: 10.1002/anie.201207554
[64]	Chen, S.; Shen, S.; Liu, G.; Qi, Y.; Zhang, F.; Li, C. Angew. Chem. Int. Ed. 2015, 54, 3047. doi: 10.1002/anie.201409906
[65]	Zhang, F.; Yamakata, A.; Maeda, K.; Moriya, Y.; Takata, T.; Kubota, J.; Teshima, K.; Oishi, S.; Domen, K. J. Am. Chem. Soc. 2012, 134, 8348. doi: 10.1021/ja301726c
[66]	Wen, F.; Wang, X.; Huang, L.; Ma, G.; Yang, J.; Li, C. ChemSusChem 2012, 5, 849. doi: 10.1002/cssc.201200190
[67]	Wen, F.; Yang, J.; Zong, X.; Ma, B.; Wang, D.; Li, C. J. Catal. 2011, 281, 318. doi: 10.1016/j.jcat.2011.05.015
[68]	Yan, H.; Yang, J.; Ma, G.; Wu, G.; Zong, X.; Lei, Z.; Shi, J.; Li, C. Angew. Chem. Int. Ed. 2009, 266, 165.
[69]	Sakata, Y.; Hayashi, T.; Yasunaga, R.; Yanaga, N.; Imamura, H. Chem. Commun. 2015, 51, 12935. doi: 10.1039/C5CC03483C
[70]	Takata, T.; Jiang, J.; Sakata, Y.; Nakabayashi, M.; Shibata, N.; Nandal, V.; Seki, K.; Hisatomi, T.; Domen, K. Nature 2020, 581, 411. doi: 10.1038/s41586-020-2278-9
[71]	Nishiyama, H.; Yamada, T.; Nakabayashi, M.; Maehara, Y.; Yamaguchi, M.; Kuromiya, Y.; Nagatsuma, Y.; Tokudome, H.; Akiyama, S.; Watanabe, T.; Narushima, R.; Okunaka, S.; Shibata, N.; Takata, T.; Hisatomi, T.; Domen, K. Nature 2021, 598, 304. doi: 10.1038/s41586-021-03907-3
[72]	Zou, Z.; Ye, J.; Sayama, K.; Arakawa, H. Nature 2001, 414, 625. doi: 10.1038/414625a
[73]	Pan, C.; Takata, T.; Nakabayashi, M.; Matsumoto, T.; Shibata, N.; Ikuhara, Y.; Domen, K. Angew. Chem. Int. Ed. 2015, 54, 2955. doi: 10.1002/anie.201410961
[74]	Maeda, K.; Teramura, K.; Lu, D.; Takata, T.; Saito, N.; Inoue, Y.; Domen, K. Nature 2006, 440, 295. doi: 10.1038/440295a
[75]	Bard, A. J. J. Photochem. 1979, 10, 59. doi: 10.1016/0047-2670(79)80037-4
[76]	Kudo, A. MRS Bulletin 2011, 36, 32. doi: 10.1557/mrs.2010.3
[77]	Maeda, K. ACS Catal. 2013, 3, 1486. doi: 10.1021/cs4002089
[78]	Li, H.; Tu, W.; Zhou, Y.; Zou, Z. Adv. Sci. 2016, 3, 1500389. doi: 10.1002/advs.201500389
[79]	Wang, W.; Chen, J.; Li, C.; Tian, W. Nat. Commun. 2014, 5, 4647. doi: 10.1038/ncomms5647
[80]	Ma, S. S. K.; Maeda, K.; Abe, R.; Domen, K. Energy Environ. Sci. 2012, 5, 8390. doi: 10.1039/c2ee21801a
[81]	Qi, Y.; Chen, S.; Cui, J.; Wang, Z.; Zhang, F.; Li, C. Appl. Catal. B: Environ. 2018, 224, 579. doi: 10.1016/j.apcatb.2017.10.041
[82]	Zhou, P.; Yu, J.; Jaroniec, M. Adv. Mater. 2014, 26, 4920. doi: 10.1002/adma.201400288
[83]	Wang, Q.; Hisatomi, T.; Jia, Q.; Tokudome, H.; Zhong, M.; Wang, C.; Pan, Z.; Takata, T.; Nakabayashi, M.; Shibata, N.; Li, Y.; Sharp, I. D.; Kudo, A.; Yamada, T.; Domen, K. Nat. Mater. 2016, 15, 611. doi: 10.1038/nmat4589
[84]	Iwase, A.; Yoshino, S.; Takayama, T.; Ng, Y. H.; Amal, R.; Kudo, A. J. Am. Chem. Soc. 2016, 138, 10260. doi: 10.1021/jacs.6b05304

太阳能光催化分解水制氢^※

Photocatalytic Water Splitting for Hydrogen Production^※

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 9

参考文献 84

相关文章 15

编辑推荐

相关统计

本文评价

[1]	陈健强, 朱钢国, 吴劼. 镍催化氮杂环丙烷的开环偶联反应研究[J]. 化学学报, 2024, 82(2): 190-212.
[2]	吴宇晗, 张栋栋, 尹宏宇, 陈正男, 赵文, 匙玉华. “双碳”目标下Janus In₂S₂X光催化还原CO₂的密度泛函理论研究[J]. 化学学报, 2023, 81(9): 1148-1156.
[3]	刘嘉文, 林玮璜, 王惟嘉, 郭学益, 杨英. Cu_1.94S-SnS纳米异质结的合成及其光催化降解研究[J]. 化学学报, 2023, 81(7): 725-734.
[4]	何明慧, 叶子秋, 林桂庆, 尹晟, 黄心翊, 周旭, 尹颖, 桂波, 汪成. 卟啉基共价有机框架的光催化研究进展^★[J]. 化学学报, 2023, 81(7): 784-792.
[5]	刘坜, 郑刚, 范国强, 杜洪光, 谭嘉靖. 4-酰基/氨基羰基/烷氧羰基取代汉斯酯参与的有机反应研究进展[J]. 化学学报, 2023, 81(6): 657-668.
[6]	李飞, 丁汇丽, 李超忠. 基于氟仿衍生的三氟甲基硼络合物参与的烯烃氢三氟甲基化反应[J]. 化学学报, 2023, 81(6): 577-581.
[7]	徐袁利, 潘辉, 杨义, 左智伟. 连续流条件下蒽-铈协同催化的苄位碳氢键选择性氧化反应^★[J]. 化学学报, 2023, 81(5): 435-440.
[8]	齐学平, 王飞, 张健. 后合成法构筑钛基金属有机框架及其应用[J]. 化学学报, 2023, 81(5): 548-558.
[9]	陈健强, 朱钢国, 吴劼. 草酸酯类化合物在自由基脱羟基化反应中的研究进展[J]. 化学学报, 2023, 81(11): 1609-1623.
[10]	杨春晖, 陈景超, 李新汉, 孟丽, 王凯民, 孙蔚青, 樊保敏. 可见光催化的硅烷二氟烯丙基化反应[J]. 化学学报, 2023, 81(1): 1-5.
[11]	解众舒, 薛中鑫, 许子文, 李倩, 王洪宇, 李维实. 石墨相氮化碳的共轭交联修饰及其对可见光催化产氢性能的影响[J]. 化学学报, 2022, 80(9): 1231-1237.
[12]	舒恒, 包义德日根, 那永. CdS基纳米管光催化氧化5-羟甲基糠醛选择性生成2,5-呋喃二甲醛[J]. 化学学报, 2022, 80(5): 607-613.
[13]	龚雪, 马新国, 万锋达, 段汪洋, 杨小玲, 朱进容. 二维单层MoSi₂X₄ (X=N, P, As)的电子结构及光学性质研究[J]. 化学学报, 2022, 80(4): 510-516.
[14]	安攀, 张庆慧, 杨状, 武佳星, 张佳颖, 王雅君, 李宇明, 姜桂元. 双碳目标下太阳能制氢技术的研究进展[J]. 化学学报, 2022, 80(12): 1629-1642.
[15]	于潇涵, 黄伟, 李彦光. 二维共价有机框架材料的可控合成及其光催化应用研究进展[J]. 化学学报, 2022, 80(11): 1494-1506.

太阳能光催化分解水制氢※

Photocatalytic Water Splitting for Hydrogen Production※

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 9

参考文献 84

相关文章 15

编辑推荐

相关统计

本文评价

太阳能光催化分解水制氢^※

Photocatalytic Water Splitting for Hydrogen Production^※