Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (11): 1124-1127. Previous Articles     Next Articles

Original Articles

二苯甲硫酮与共轭双烯化合物的Diels-Alder反应

黄锦珂;金毅   

  1. 中山大学化学系
  • 发布日期:1989-11-15

The diels-alder reactions of thiobenzophenone to conjugated diene compounds

HUANG JINKE;JIN YI   

  • Published:1989-11-15

The Diels-Alder reactions of thiobenzophenone trans-1-phenyl-1,3-butadiene, Me trans-2,4-pentadienoate, and trans-1,3-pentadiene, were investigated. These reactions are stereospecific. The structure of adducts I (R = Ph, CO2Me, Me) and their corresponding sulfones have been determine by the study of spectroscopic data.

Key words: THIOKETONE, OXIDATION, DIPHENYLMETHANONE, SELECTIVITY, PROTON MAGNETIC RESONANCE SPECTROMETRY, CONJUGATED DOUBLE BOND COMPOUNDS, CHEMICAL SHIFT, REGION, STEREOCHEMISTRY, ADDITION REACTION

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