MSCV studies of electroreduction of unsaturated alcohols:II. electroreduction of propargyl alcohol

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (2): 155-160. Previous Articles Next Articles

Original Articles

不饱和醇电还原的质谱-电化学循环伏安(MSCV)法研究:II.炔丙醇的电还原

刘佩芳;陈剑;王辉;查全性

武汉大学化学系电化学研究室

发布日期:1993-02-15

MSCV studies of electroreduction of unsaturated alcohols:II. electroreduction of propargyl alcohol

LIU PEIFANG;CHEN JIAN;WANG HUI;CHA QUANXING

Published:1993-02-15

Abstract

Results from MSCV (Mass spectrometric cyclic voltammetry) studies for electroreduction of propargyl alcoholat Pt porous electrodeson 0.5mol.dm^-3HCLO4 indicate that C-OH bond may be cleaved in both allyl and propargyl groupsfollowed by forming propene and propane .besides a small mamount of propargyl alcohol is directly protomated to allyl alcohol.the mass current (IM)-potential (Φ)relationship of the fragments provide detailed information for the constituent range and their tafel slops were obtained. possible mechanisms are discussed based on the experimental results.

Key words: REACTION MECHANISM, PROPYNOL, ELECTROLYSIS OF CHLORIDE

CLC Number:

O646

Cite this article

LIU PEIFANG;CHEN JIAN;WANG HUI;CHA QUANXING. MSCV studies of electroreduction of unsaturated alcohols:II. electroreduction of propargyl alcohol[J]. Acta Chimica Sinica, 1993, 51(2): 155-160.

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不饱和醇电还原的质谱-电化学循环伏安(MSCV)法研究:II.炔丙醇的电还原

MSCV studies of electroreduction of unsaturated alcohols:II. electroreduction of propargyl alcohol

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