Nucleophilic addition of silyl enol ethers to [60] fullerene

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (10): 1646-1652. Previous Articles Next Articles

Original Articles

烯醇硅醚对[60]富勒烯的亲核加成反应

高翊;张丹维;舒联合;孙卫权;张隽;吴世晖;吴厚铭

复旦大学化学系.上海(200433);中国科学院上海有机化学研究所.上海(200032)

发布日期:2001-10-15

Nucleophilic addition of silyl enol ethers to [60] fullerene

Gao Yi;Zhang Danwei;Shu Lianhe;Sun Weiquan;Zhang Juan;Wu Shihui;Wu Houming

Fudan Univ, Dept Chem.Shanghai(200433);Shanghai Inst Organ Chem., CAS.Shanghai(200032)

Published:2001-10-15

Abstract

1-(4-Methoxyphenyl)-1-(trimethylsilyloxy)ethylene was reacted with [60] fullerene in air atmosphere and nonpolar solvent (toluene) to form an unpredicted product of cyclopropano [60] fullerene derivative (5). In the presence of polar aprotic solvent, tetrahydrofuran, and under non- oxygen condition, the normal nucleophilic addition product 1,2-substituted [60] fullerene (3) was obtained. A reasonable mechanism has been suggested.

Key words: FULLERENES, NUCLEOPHILIC REACTION, ADDITION REACTION, REACTION MECHANISM

CLC Number:

O621

Cite this article

Gao Yi;Zhang Danwei;Shu Lianhe;Sun Weiquan;Zhang Juan;Wu Shihui;Wu Houming. Nucleophilic addition of silyl enol ethers to [60] fullerene[J]. Acta Chimica Sinica, 2001, 59(10): 1646-1652.

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烯醇硅醚对[60]富勒烯的亲核加成反应

Nucleophilic addition of silyl enol ethers to [60] fullerene

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