Oxidation Kinetics of Calcium Sulfite Catalyzed by Peracetic Acid

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (14): 1500-1506. Previous Articles Next Articles

Original Articles

过氧乙酸催化氧化亚硫酸钙的反应动力学

赵毅*^,1，汪黎东¹，王小明²，贾烁华³

(¹华北电力大学环境科学与工程学院保定 071003)
(²国电南京电力环境保护研究所南京 210031)
(³山西电力科学研究院太原 030001)

投稿日期:2005-10-27 修回日期:2006-03-16 发布日期:2006-07-28
通讯作者: 赵毅

Oxidation Kinetics of Calcium Sulfite Catalyzed by Peracetic Acid

ZHAO Yi*^,1, WANG Li-Dong¹, WANG Xiao-Ming², JIA Shuo-Hua³

(¹School of Environmental Science and Engineering, North China Electric Power University, Baoding 071003)
(²National Power Environmental Protection Research Institute, Nanjing 210031)
(³Shanxi Electric Power Research Institute, Taiyuan 030001)

Received:2005-10-27 Revised:2006-03-16 Published:2006-07-28
Contact: ZHAO Yi

Abstract

The intrinsic oxidation kinetics of sodium sulfite catalyzed by peracetic acid was studied by intermittent apparatus with reaction orders of the reagents and activation energy achieved. By bubbling apparatus, the macroscopic oxidation kinetics of calcium sulfite catalyzed by peracetic acid was investigated via variation of pH, concentration of calcium sulfite and peracetic acid, airflow flux and temperature.

Key words: peracetic acid, sulfite, oxidation, reaction, kinetics

Cite this article

ZHAO Yi*^,1, WANG Li-Dong, WANG Xiao-Ming², JIA Shuo-Hua³. Oxidation Kinetics of Calcium Sulfite Catalyzed by Peracetic Acid[J]. Acta Chimica Sinica, 2006, 64(14): 1500-1506.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Guanglong Huang, Xiao-Song Xue. Computational Study on the Mechanism of Chen’s Reagent as Trifluoromethyl Source [J]. Acta Chimica Sinica, 2024, 82(2): 132-137.
[2]	Shenna Deng, Changchun Peng, Yunhong Niu, Yun Xu, Yunxiao Zhang, Xiang Chen, Hongmin Wang, Shanshan Liu, Xiao Shen. Radical Brook Rearrangement Mediated Olefin Difunctionalization Involving α-Fluoroalkyl-α-silyl Methanols [J]. Acta Chimica Sinica, 2024, 82(2): 119-125.
[3]	Weiyang Gao, Weichao Deng, Yang Gao, Renxiao Liang, Yixia Jia. Intermolecular Enantioselective Dearomative Oxidative Heck Reaction of Indoles [J]. Acta Chimica Sinica, 2024, 82(1): 1-4.
[4]	Zhiqiang Wang, Jinzhan Su. Investigation of the Kinetic Properties and Photoelectrochemical Water Splitting of Cu₃V₂O₈/ZnO Photoanode Modified by Cobalt Phosphate [J]. Acta Chimica Sinica, 2024, 82(1): 26-35.
[5]	Ping Li, Qiyu Yang, Jing Zeng, Ran Zhang, Qiuyan Chen, Fei Yan. Effect of Fluorine Doping on the Performance of Reversible Solid Oxide Cells and Related Kinetic Studies [J]. Acta Chimica Sinica, 2024, 82(1): 36-45.
[6]	Guoqing Cui, Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu. Research Progress on the Design, Preparation and Properties of Catalysts for CO₂ Hydrogenation to Alcohols [J]. Acta Chimica Sinica, 2023, 81(8): 1081-1100.
[7]	Jianghao Luo, Haowen Ma, Jiehao Zhang, Wei Zhou, Qian Cai. Synthesis of Pyrrolo[3,2-d]pyrimidin-4-ones via Cascade Alkyne−isocyanide [3＋2] Cycloaddition/Boulton-Katritzky Rearrangement/Ring Expansion Process^★ [J]. Acta Chimica Sinica, 2023, 81(8): 898-904.
[8]	Xinpu Fu, Xiuling Wang, Weiwei Wang, Rui Si, Chunjiang Jia. Fabrication and Mechanism Study of Clustered Au/CeO₂ Catalyst for the CO Oxidation Reaction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 874-883.
[9]	Jianchuan Liu, Cuiyan Li, Yaozu Liu, Yujie Wang, Qianrong Fang. Highly-Stable Two-Dimensional Bicarbazole-based sp²-Carbon-conjugated Covalent Organic Framework for Efficient Electrocatalytic Oxygen Reduction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 884-890.
[10]	Shaoyan Gan, Shengyu Zhong, Liting Wang, Lei Shi. Synthesis and Application of Organic Hypervalent Bromine Reagents [J]. Acta Chimica Sinica, 2023, 81(8): 1030-1042.
[11]	Zeng Chongyang, Hu Ping, Wang Biqin, Fang Wenyan, Zhao Keqing, Donnio Bertrand. Star-shaped Triphenylene-triazine Multi-stimuli Responsive Discotic Liquid Crystals: Synthesis, Properties and Applications [J]. Acta Chimica Sinica, 2023, 81(5): 469-479.
[12]	Wang Rui-Xiang, Zhao Qing-Ru, Gu Qing, You Shu-Li. Gold/Iridium Catalyzed Alkynylamide Cyclization/Asymmetric Allylic Benzylation Cascade Reaction^★ [J]. Acta Chimica Sinica, 2023, 81(5): 431-434.
[13]	Xu Yuanli, Pan Hui, Yang Yi, Zuo Zhiwei. Selectively Aerobic Oxidation of Benzylic C—H Bonds Enabled by Dual Anthracene and Cerium Catalysis under Continuous-Flow Conditions^★ [J]. Acta Chimica Sinica, 2023, 81(5): 435-440.
[14]	Yuan Fangyan, Li Chao, Luo Meiming, Zeng Xiaoming. Chromium-Catalyzed Carbonyl-Carbonyl Deoxygenative Couplings of Ketones to Tetrasubstituted Olefins^★ [J]. Acta Chimica Sinica, 2023, 81(5): 456-460.
[15]	Mingliang Han, Lihua Xu. Progress on the Transition Metal-catalyzed Cross-coupling Reaction of Thioesters [J]. Acta Chimica Sinica, 2023, 81(4): 381-392.

过氧乙酸催化氧化亚硫酸钙的反应动力学

Oxidation Kinetics of Calcium Sulfite Catalyzed by Peracetic Acid

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments