Solid state reactions of coordination compounds XXXIX.  The solid state reactions between K~2[Ni(CN)~4].H~2O and  some organic acids at room temperature

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (12): 1473-1477. Previous Articles Next Articles

Original Articles

固相配位化学反应研究XXXIX. 四氰合镍酸钾与固体有机酸在室温下的固相反应

郑丽敏;忻新泉;梅毓华

南京大学配位化学研究所.南京(210008)

发布日期:1991-12-15

Solid state reactions of coordination compounds XXXIX. The solid state reactions between K~2[Ni(CN)~4].H~2O and some organic acids at room temperature

Zheng Limin;Xin Xinquan;Mei Yuhua

Najing Univ, Inst Coordinat Chem.Nanjing(210008)

Published:1991-12-15

Abstract

In this paper, the solid state reactions between potassium tetracyanonickelate(II) and oxalic, malonic, fumaric, succinic, adipic acid are studied, followed by modern techniques such as IR, DRS, XRD and MS. It is found that the reactions occur at room temperature. Ni(CN)~2.xH~2O is obtained as a main product and HCN gas is detected. The acidity of these solid organic acids decreases in the order: oxalic>malonic>fumaric>succinic>adipic acid. Proton is believed to play an important role in the reaction process. And the possible mechanism is discussed.

Key words: INFRA-RED, DIFFUSE REFLECTION, UV-DETECTOR, OXALIC ACID, MALONIC ACID, BUTANEDIOIC ACID, HEXANEDIOIC ACID, REACTION MECHANISM

CLC Number:

O621

Cite this article

Zheng Limin;Xin Xinquan;Mei Yuhua. Solid state reactions of coordination compounds XXXIX. The solid state reactions between K~2[Ni(CN)~4].H~2O and some organic acids at room temperature[J]. Acta Chimica Sinica, 1991, 49(12): 1473-1477.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Guanglong Huang, Xiao-Song Xue. Computational Study on the Mechanism of Chen’s Reagent as Trifluoromethyl Source [J]. Acta Chimica Sinica, 2024, 82(2): 132-137.
[2]	Guoqing Cui, Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu. Research Progress on the Design, Preparation and Properties of Catalysts for CO₂ Hydrogenation to Alcohols [J]. Acta Chimica Sinica, 2023, 81(8): 1081-1100.
[3]	Xinpu Fu, Xiuling Wang, Weiwei Wang, Rui Si, Chunjiang Jia. Fabrication and Mechanism Study of Clustered Au/CeO₂ Catalyst for the CO Oxidation Reaction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 874-883.
[4]	Luocong Wang, Zhewei Li, Caiwei Yue, Peihuan Zhang, Ming Lei, Min Pu. Theoretical Study on the Isomerization Mechanism of Azobenzene Derivatives under Electric Field [J]. Acta Chimica Sinica, 2022, 80(6): 781-787.
[5]	Siming Yang, Airong Liu, Jing Liu, Zhaoli Liu, Weixian Zhang. Advance of Sulfidated Nanoscale Zero-Valent Iron: Synthesis, Properties and Environmental Application [J]. Acta Chimica Sinica, 2022, 80(11): 1536-1554.
[6]	Yilong Hua, Donghan Li, Tianhang Gu, Wei Wang, Ruofan Li, Jianping Yang, Wei-xian Zhang. Enrichment of Uranium from Aqueous Solutions with Nanoscale Zero-valent Iron: Surface Chemistry and Application Prospect [J]. Acta Chimica Sinica, 2021, 79(8): 1008-1022.
[7]	Huang Rongyi, Shen Qiong, Zhang Chao, Zhang Shaoyong, Xu Heng. Studies on the Mechanism of the Transition Metal-Catalyzed Reaction of Organonitrile with Sodium Azide [J]. Acta Chimica Sinica, 2020, 78(6): 565-571.
[8]	Wu Weirong, Yuan Xiaomin, Hou Hua, Wang Baoshan. Theoretical Investigations on the Mechanisms for the Reactions of Sevoflurane Radicals[(CF₃)₂C(·)OCH₂F, (CF₃)₂CHOC(·)HF] with O₂and the OH· Radicals Regeneration [J]. Acta Chim. Sinica, 2018, 76(10): 793-801.
[9]	Mu Weihua, Ma Yao, Fang Decai, Wang Rong, Zhang Haina. Computational Insights into the Diels-Alder-alike Reactions of 1-Iodo-2-Lithio-o-Carborane with Fulvenes [J]. Acta Chim. Sinica, 2018, 76(1): 55-61.
[10]	Huang Xiao-yue, Wang Wei, Ling Lan, Zhang Wei-xian. Heavy Metal-nZVI Reactions: the Core-shell Structure and Applications for Heavy Metal Treatment [J]. Acta Chim. Sinica, 2017, 75(6): 529-537.
[11]	Tang Jing, Tang Lin, Feng Haopeng, Dong Haoran, Zhang Yi, Liu Sishi, Zeng Guangming. Research Progress of Aqueous Pollutants Removal by Sulfidated Nanoscale Zero-valent Iron [J]. Acta Chim. Sinica, 2017, 75(6): 575-582.
[12]	Ding Shuang, Ge Qingfeng, Zhu Xinli. Research Progress in Ketonization of Biomass-derived Carboxylic Acids over Metal Oxides [J]. Acta Chim. Sinica, 2017, 75(5): 439-447.
[13]	Yang Zhen, Xue Yijiang, He Yuanhang. Thermal Sensitivity of CL20/DNB Co-crystal Research via Molecular Dynamics Simulations [J]. Acta Chim. Sinica, 2016, 74(7): 612-619.
[14]	Ma Jun, Li Rong, Ren Kuiwei, Ma Xilong, Zhu Kaili, Geng Zhiyuan. Mechanism and Spin-orbit Coupling Study for Two State Reaction Ni₂⁺ with Cyclohexane [J]. Acta Chim. Sinica, 2015, 73(5): 431-440.
[15]	Wang Ying, Zhang Limin, Hu Tianjun. Progress in Oxygen Reduction Reaction Electrocatalysts for Metal-Air Batteries [J]. Acta Chim. Sinica, 2015, 73(4): 316-325.

固相配位化学反应研究XXXIX. 四氰合镍酸钾与固体有机酸在室温下的固相反应

Solid state reactions of coordination compounds XXXIX. The solid state reactions between K~2[Ni(CN)~4].H~2O and some organic acids at room temperature

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

固相配位化学反应研究XXXIX. 四氰合镍酸钾与固体有机酸在室 温下的固相反应

Solid state reactions of coordination compounds XXXIX. The solid state reactions between K~2[Ni(CN)~4].H~2O and some organic acids at room temperature

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

固相配位化学反应研究XXXIX. 四氰合镍酸钾与固体有机酸在室温下的固相反应