Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (3): 280-284. Previous Articles     Next Articles

Original Articles

固相配位化学反应研究LVIII.2, 2'-对苯二甲硫基二乙酸与醋酸铜在低热温度下的固相化学反应

张卫华;王建华;郑丽敏;忻新泉   

  1. 南京大学配位化学国家重点实验室
  • 发布日期:1994-03-15

Studies on the solid state reactions of coordination compounds. LVIII. the solid-solid state reaction of 2,2'-(p-phenylenedimethylenethio)diacetic acid with copper acetate monohydrate at low heating temperature

ZHANG WEIHUA;WANG JIANHUA;ZHENG LIMIN;XIN XINQUAN   

  • Published:1994-03-15

The solid-solid state reaction of 2,2'-(p-phenylenedimethylenethio)diacetic acid with copper acetate monohydrate was studied. XRD, IR, ESR and elemental anal. were used to characterize the solid product. The kinetics of the isothermal solid state reaction was investigated by using the elec. conductivity measurement. A possible mechanism is discussed, and kinetic parameters were calculated

Key words: REACTION MECHANISM, INFRARED SPECTROPHOTOMETRY, X-RAY DIFFRACTION ANALYSIS, ELECTRON SPIN RESONANCE, SOLID PHASE REACTION, KINETICS PARAMETER

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