Preparation, molecular structure and thermal decomposition mechanism of [Pb(NTO)~2(H~2O)]

Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (6): 545-550. Previous Articles Next Articles

Original Articles

[Pb(NTO)~2(H~2O)]的制备, 分子结构和热分解机理的研究

张同来;胡荣祖;李福平;郁开北

西安近代化学研究所;中国科学院成都分院

发布日期:1994-06-15

Preparation, molecular structure and thermal decomposition mechanism of [Pb(NTO)~2(H~2O)]

ZHANG TONGLAI;HU RONGZU;LI FUPING;YU KAIBEI

Published:1994-06-15

Abstract

= 3-nitro-1,2,4-triazol-5-one) and lead nitrate. It was characterized by thermal anal., elemental anal., 13C NMR and IR measurement. The crystal structure of [Pb(NTO)2(H2O)] was determine by single crystal diffraction anal. The crystal belongs to space group P21/n with a 0.7284(2), b 1.2166(3), c 1.2310(3) nm, b 90.36(2)? Z = 4, dc = 2.96 g譪m-3, R = 0.0667. Based on the thermal anal., the thermal decomposition mechanism of [Pb(NTO)2(H2O)] was derived.

Key words: CRYSTAL STRUCTURE DETERMINATION, NITRO COMPOUNDS, REACTION MECHANISM, MOLECULAR STRUCTURE, SINGLE CRYSTALS, LEAD COMPLEX, THERMAL DECOMPOSITION

CLC Number:

O611.662
O74

Cite this article

ZHANG TONGLAI;HU RONGZU;LI FUPING;YU KAIBEI. Preparation, molecular structure and thermal decomposition mechanism of [Pb(NTO)~2(H~2O)][J]. Acta Chimica Sinica, 1994, 52(6): 545-550.

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[Pb(NTO)~2(H~2O)]的制备, 分子结构和热分解机理的研究

Preparation, molecular structure and thermal decomposition mechanism of [Pb(NTO)~2(H~2O)]

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