Synthesis and photochromism of aryl substituted fulgides

Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (7): 716-721. Previous Articles Next Articles

Original Articles

芳环取代的俘精酸酐的合成及光致变色反应研究

于联合;明阳福;樊美公;姚思德;林念云

中国科学院感光化学研究所;中国科学院上海原子核研究所;中国科学院辐射化学开放实验室

发布日期:1996-07-15

Synthesis and photochromism of aryl substituted fulgides

YU LIANHE;MING YANGFU;FAN MEIGONG;YAO SIDE;LIN NIANYUN

Published:1996-07-15

Abstract

In this paper, we report the synthesis and photochromism of four aryl fulgides: (E)-1-(p-methoxyphenyl) ethylidene (isopropylidene) succinic anhydride (BF1), (E)-1-(p-methoxyphenyl) ethylidene (isobutylidene) succinic anhydride (BF2), (E)-α-naphthylethylidene (isopropylidene) succinic anhydride (NF1), (E)-β-naphthylethylidene (isopropylidene) succinic anhydride (NF2). Photochromic processes of these compounds have been studied by nanosecond laser flash photolysis technique, the reaction mechanism has been discussed. It was found that photoinduced cyclization of aryl fulgides is a fast process, and only the excited signlet state is involved in the photocyclization reaction.

Key words: ABSORPTION SPECTROMETRY, REACTION MECHANISM, PHOTOCHROMISM, FLASH PHOTOLYSIS

CLC Number:

O644

Cite this article

YU LIANHE;MING YANGFU;FAN MEIGONG;YAO SIDE;LIN NIANYUN. Synthesis and photochromism of aryl substituted fulgides[J]. Acta Chimica Sinica, 1996, 54(7): 716-721.

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芳环取代的俘精酸酐的合成及光致变色反应研究

Synthesis and photochromism of aryl substituted fulgides

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