Preparation of CS-CMC Polyelectrolyte Membrane and Its, Application to Electro-generation of FeO42-

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (8): 784-788. Previous Articles Next Articles

Original Articles

CS-CMC聚合物电解质膜的制备及在电生成FeO₄^2-中的应用

许彩霞，陈日耀，郑曦，黄振霞，黄雪红，陈震*

(福建师范大学化学与材料学院福州 350007)

投稿日期:2005-07-20 修回日期:2005-12-27 发布日期:2006-04-25
通讯作者: 陈震

Preparation of CS-CMC Polyelectrolyte Membrane and Its, Application to Electro-generation of FeO₄^2-

XU Cai-Xia, CHEN Ri-Yao, ZHENG Xi, HUANG Zhen-Xia, HUANG Xue-Hong, CHEN Zhen*

(College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007)

Received:2005-07-20 Revised:2005-12-27 Published:2006-04-25
Contact: CHEN Zhen

Abstract

The polyelectrolyte membrane was prepared by interaction between chitosan (CS) and carboxymethylcellulose (CMC) using glutaraldehyde as linkage reagent. SEM was used to observe its surface structure, while IR spectrum indicated that the polymer membrane has COOH and NH₃⁺ functional groups and displays character of the amphoteric ion. Compared to CS or CMC membranes, CS-CMC membrane was stable in acid or alkali solution. The structure and properties were studied and the results show that the membrane can be used as a separator in electro-generation of FeO₄^2-.

Key words: polyelectrolyte, chitosan, carboxymethylcellulose, glutaraldehyde, ferrate, electrolyte

Cite this article

XU Cai-Xia, CHEN Ri-Yao, ZHENG Xi, HUANG Zhen-Xia, HUANG Xue-Hong, CHEN Zhen*. Preparation of CS-CMC Polyelectrolyte Membrane and Its, Application to Electro-generation of FeO₄^2-[J]. Acta Chimica Sinica, 2006, 64(8): 784-788.

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CS-CMC聚合物电解质膜的制备及在电生成FeO₄^2-中的应用

Preparation of CS-CMC Polyelectrolyte Membrane and Its, Application to Electro-generation of FeO₄^2-

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CS-CMC聚合物电解质膜的制备及在电生成FeO42-中的应用