有机化学 ›› 2012, Vol. ›› Issue (03): 433-443.DOI: 10.6023/cjoc1106222 上一篇    下一篇

综述与进展

过渡金属催化氮杂二环烯烃不对称开环反应的研究进展

程汉超, 梁秀丽, 李晓璐, 龙玉华, 杨定乔   

  1. 华南师范大学化学与环境学院 广州 510006
  • 收稿日期:2011-06-22 修回日期:2011-09-30 发布日期:2012-03-24
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21172081)和广东省自然科学基金(No. 8251063101000002)资助项目.

Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Azabicyclic Alkenes

Cheng Hanchao, Liang Xiuli, Li Xiaolu, Long Yuhua, Yang Dingqiao   

  1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006
  • Received:2011-06-22 Revised:2011-09-30 Published:2012-03-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21172081) and the Natural Science Foundation of Guangdong Province (No. 8251063101000002).

综述了近年来过渡金属催化氮杂二环烯烃的开环反应的研究进展, 重点讨论了过渡金属催化剂的种类、亲核试剂的类型、配体、底物氮杂二环烯烃及其衍生物的结构、溶剂和添加剂等因素对开环反应的影响, 并对开环反应的可能的机理进行了讨论.

关键词: 氮杂二环烯烃, 过渡金属, 催化, 开环反应

The recent progress in transition metal-catalyzed ring-opening reactions of azabicyclic alkenes was reviewed focused on the influence of the types of transition metal catalysts, nucleophiles, ligands, the structures of azabicyclic alkenes and its derivatives, solvents and additives on the ring-opening reactions. Moreover, the possible mechanisms of the ring-opening reactions were also discussed.

Key words: azabicyclic alkenes, transition metal, catalyze, ring-opening reaction