有机化学 ›› 2012, Vol. ›› Issue (03): 616-620.DOI: 10.6023/cjoc1107011 上一篇    下一篇

研究简报

水溶液中一步合成二吡咯甲烷类化合物

吴振豪, 胡江磊, 王凯凯, 高超, 王洪宇, 张龙   

  1. 长春工业大学吉林省石化资源与生物质综合利用工程实验室 长春 130012
  • 收稿日期:2011-07-01 修回日期:2011-08-27 发布日期:2012-03-24
  • 通讯作者: 张龙 E-mail:zhanghongzhl@163.com

One-Step Synthesis of Dipyrromethanes in Water

Wu Zhenhao, Hu Jianglei, Wang Kaikai, Gao Chao, Wang Hongyu, Zhang Long   

  1. Jilin Provincial Engineering Laboratory for the Complex Utilization of Petro Resources and Biomass, Changchun University of Technology, Changchun 130012
  • Received:2011-07-01 Revised:2011-08-27 Published:2012-03-24

在水相中, 以磷钨酸为催化剂, 吡咯与羰基化合物为底物, 室温下一步合成了二吡咯甲烷类化合物, 反应产物纯度高, 无需进一步纯化. 该方法具有明显的环境友好、产率高和操作过程简便的优点.

关键词: 二吡咯甲烷, 吡咯, 羰基化合物, 水, 绿色化学

A novel and non-conventional synthesis of meso-substitued dipyrromethanes under the catalysis of H3PW12O40 in water at room temperature is described in this paper. The reactions were performed under mild conditions, affording various dipyrrometnanes in good to excellent yields and high purity.

Key words: dipyrromethane, pyrrole, carbonyl compound, water, green chemistry