有机化学 ›› 2012, Vol. 32 ›› Issue (06): 994-1009.DOI: 10.6023/cjoc1202073 上一篇    下一篇

综述与进展

炔烃偶联反应研究的新进展(特邀稿件)

白东虎a, 李春举a, 李健a, 贾学顺a,b   

  1. a 上海大学化学系 上海 200444;
    b 中国科学院上海有机化学研究所天然产物有机合成化学重点实验室 上海 200032
  • 收稿日期:2012-02-07 修回日期:2012-03-26 发布日期:2012-04-10
  • 通讯作者: 贾学顺 E-mail:xsjia@mail.shu.edu.cn
  • 基金资助:

    国家自然科学基金(21142012, 21002061, 20902057)和中国科学院上海有机化学研究所天然产物有机合成化学重点实验室基金支持

New Progress of Acetylene-Coupling Reactions

Bai Donghua, Li Chunjua, Li Jiana, Jia Xueshuna,b   

  1. a Department of Chemistry, Shanghai University, Shanghai, 200444, China;
    b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
  • Received:2012-02-07 Revised:2012-03-26 Published:2012-04-10
  • Supported by:

    Project supported by the the National Natural Science Foundation of China (No: 21142012, 21002061, 20902057), the Key Laboratory of Synthetic Chemistry of Natural Substances, Chinese Academy of Sciences.

综述了近几年来炔偶联反应的新进展,主要涉及铜试剂和钯试剂催化的端炔偶联反应以及反应机理和应用。

关键词: 炔, 炔偶联, 铜催化, 钯催化, 反应

The recent studies of acetylene-coupling reactions are reviewed, mainly focusing on copper reagents and palladium reagents catalyzed coupling reactions of terminal alkyne as well as the reaction mechanism and application.

Key words: alkyne, alkyne coupling, copper catalysis, palladium catalysis, reaction