有机化学 ›› 2012, Vol. 32 ›› Issue (11): 2073-2080.DOI: 10.6023/cjoc1202162 上一篇    下一篇

综述与进展

金催化的C—C偶联反应研究进展

张艳a, 罗莎a, 朱成建b   

  1. a 江南大学医药学院 无锡 214122;
    b 南京大学化学化工学院 南京 210093
  • 收稿日期:2012-02-16 修回日期:2012-05-16 发布日期:2012-06-01
  • 通讯作者: 张艳 E-mail:zhangyanchem@163.com
  • 基金资助:

    国家自然科学基金(Nos. 20832001, 20972065, 21074054)资助项目.

Advances in Gold-Catalyzed C—C Coupling Reactions

Zhang Yana, Luo Shaa, Zhu Chengjianb   

  1. a School of Medicine and Pharmaceutics, Jiangnan University, Wuxi 214122;
    b School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093
  • Received:2012-02-16 Revised:2012-05-16 Published:2012-06-01
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 20832001, 20972065, 21074054).

近年来金催化剂作为一种温和的π路易斯酸展现了其独特的催化性能, 已经成为有机化学研究的热点之一. 综述了近年来金催化的碳碳偶联反应, 并对其以后在氧化还原反应方面的应用进行探讨.

关键词: C—C偶联, 交叉偶联反应, 金, 均相催化

Gold, with its special properties as a mild carbophilic π Lewis acid, its ability to insert into C—bonds, and, as discovered recently, its ability to undergo redox transformations, offers the opportunity to apply all this potent proficiency for the construction of compounds in an efficient and economical way. This review critically presents the C—C coupling reactions enabled by gold catalysts to encourage further research activities in this promising area of oxidation/reduction gold catalysts.

Key words: C—C coupling, cross-coupling reactions, gold, homogeneous catalysis