有机化学 ›› 2015, Vol. 35 ›› Issue (2): 294-308.DOI: 10.6023/cjoc201409034 上一篇    下一篇

综述与进展

对甲苯磺酰腙的偶联反应研究进展

许恺, 沈冲, 单尚   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2014-08-28 修回日期:2014-10-08 发布日期:2014-11-18
  • 通讯作者: 单尚 E-mail:shanshang2001@163.com

Progress of Cross-Coupling Reaction with N-Tosylhydrazones

Xu Kai, Shen Chong, Shan Shang   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2014-08-28 Revised:2014-10-08 Published:2014-11-18

综述了近几年来对甲苯磺酰腙在有机合成中的应用新进展. 主要介绍了对甲苯磺酰腙参与的过渡金属催化的交叉偶联反应和不含金属的反应.

关键词: 对甲苯磺酰腙, 金属卡宾, 交叉偶联反应, 不含金属的反应

The recent progress in the development of the application of N-tosylhydrazones in the organic synthesis is summarized. Mainly, the advances in the areas of both metal-catalyzed cross-coupling and metal-free reactions with N-tosylhydra-zones are introduced.

Key words: N-tosylhydrazones, metal carbene, cross-coupling reactions, metal-free reactions