有机化学 ›› 2018, Vol. 38 ›› Issue (3): 555-564.DOI: 10.6023/cjoc201708039 上一篇    下一篇

所属专题: 荧光探针-生物传感合辑 有机超分子化学合辑

综述与进展

卤素离子化学传感器研究进展

廖承莉, 吴娇, 张耀辉, 党曼, 邓茵茵, 胡芳   

  1. 宁波大学材料科学与化学工程学院 宁波 315211
  • 收稿日期:2017-08-20 修回日期:2017-10-13 发布日期:2017-11-03
  • 通讯作者: 胡芳,E-mail:hufang@nbu.edu.cn E-mail:hufang@nbu.edu.cn
  • 基金资助:

    国家自然科学基金(No.21602122)、宁波市自然科学基金(No.2016A610051)、宁波大学人才项目(No.ZX2015000586)以及宁波大学王宽诚幸福基金资助项目.

Recent Progress on Chemosensors for Halogen Ions

Liao Chengli, Wu Jiao, Zhang Yaohui, Dang Man, Deng Yinyin, Hu Fang   

  1. Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211
  • Received:2017-08-20 Revised:2017-10-13 Published:2017-11-03
  • Contact: 10.6023/cjoc201708039 E-mail:hufang@nbu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21602122), the Natural Science Foundation of Ningbo City (No. 2016A610051), the Research Funds of Ningbo University (No. ZX2015000586) and the K. C. Wong Magna Fund in Ningbo University.

卤素离子在化学、生物学以及材料学等方面都具有十分重要的作用.在生物体中,氟化物浓度的大小对生物体健康有着重要的影响;卤素化合物经常作为一种阻燃剂被添加到塑料等聚合物产品中,用以提高燃点.因此对于卤素离子的检测具有特别重要的意义.光化学传感器通常是指比色和荧光传感器,它具有选择性好以及灵敏度高等优点.近年来,一些基于卤素离子的化学传感器被广泛地报道.根据主客体分子的类型,卤素离子化学传感器主要包括氟离子化学传感器、碘离子化学传感器、双通道卤素离子化学传感器以及功能化卤素离子化学传感器.综述了近年来不同类型的卤素离子化学传感器的研究进展,总结了该类传感器的合成策略,对未来卤素离子化学传感器的研究方向进行了展望.

关键词: 卤素离子, 客体, 化学传感器

Halogen ions play an important role in chemistry, biology and material. The concentration of fluoride in the organism directly affects its health. The halide materials often act as flame retardant to improve the ignition point for plastic and other polymer products. So it is of great significance to detect halogen ions. Chemosensors include colorimetric and fluorescent sensors, which have the advantages of good selectivity and high sensitivity. In recent years, some halogen ion chemosensors have been reported widely. According to the type of host and guest molecules, halgen ion chemosensors mainly include fluoride ion chemosensors, iodine ion chemosensors, dual channel chemosensors and functional chemosensors. In this paper, the progress of halogen ion chemosensors in recent years is reviewed, the synthetic strategies for them are summarized and the future research direction of halogen ion chemosensors is prospected.

Key words: halogen ion, guest, chemosensor