茂金属催化剂体系及其丙烯聚合性能调控

doi:10.6023/cjoc201803047

有机化学 ›› 2018, Vol. 38 ›› Issue (11): 2937-2992.DOI: 10.6023/cjoc201803047 上一篇下一篇

综述与进展

茂金属催化剂体系及其丙烯聚合性能调控

陈志康^a, 毛远洪^b, 曹育才^c, 梁胜彪^b, 宋莎^c, 倪晨^b, 刘振宇^b, 叶晓峰^c, 沈安^c, 朱红平^a

a 固体表面物理化学国家重点实验室厦门大学化学化工学院厦门 361005;
b 中国石化茂名石化公司茂名 525021;
c 聚烯烃催化技术与高性能材料国家重点实验室上海市聚烯烃催化技术重点实验室上海化工研究院上海 200062

收稿日期:2018-03-27 修回日期:2018-05-27 发布日期:2018-06-15
通讯作者: 梁胜彪, 朱红平 E-mail:liangshengb.mmsh@sinopec.com;hpzhu@xmu.edu.cn
基金资助:
中国石化茂名石化公司基金、聚烯烃催化技术与高性能材料国家重点实验室基金和上海市聚烯烃催化技术重点实验室基金（Nos.201501-PT-C01-005，沪CXY-2015-003，16DZ2270800，16DZ2290700）、国家自然科学基金（Nos.21473142，20673191）和教育部创新团队基金（No.IRT_14R31）资助项目.

Metallocene Catalyst Systems and Control over the Propylene Polymerization

Chen Zhikang^a, Mao Yuanhong^b, Cao Yucai^c, Liang Shengbiao^b, Song Sha^c, Ni Chen^b, Liu Zhenyu^b, Ye Xiaofeng^c, Shen An^c, Zhu Hongping^a

a State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
b Sinopec Maoming Petrochemical Company, Maoming 525011;
c State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai Research Institute of Chemical Industry, Shanghai 200062

Received:2018-03-27 Revised:2018-05-27 Published:2018-06-15
Supported by:
Project supported by the Sinopec Maoming Petrochemical Company, the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins (Nos. 201501-PT-C01-005, CXY-2015-003, 16DZ2270800, 16DZ2290700), the National Natural Science Foundation of China (Nos. 21473142, 20673191), and the Program for Innovative Research Team of Education (No. IRT_14R31).

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摘要/Abstract

国内聚丙烯的生产基本上使用传统的Ziegler-Natta催化剂，国外已经使用茂金属催化剂.茂金属催化剂生产的聚丙烯提升了产品性能，市场需求份额逐年增加，国内需要开发茂金属催化剂并拓展工业应用.茂金属催化剂与传统的Ziegler-Natta催化剂相比，结构类型丰富，反应调控能力强，可以催化生成结构多样的聚丙烯.以茂金属催化剂的发展为主线，探讨催化剂结构对反应性能的影响；分析体系中多种因素如温度、压力、催化剂浓度、助剂等对反应活性的调控；讨论催化反应机理.

关键词: 茂金属催化剂, 丙烯聚合, 反应机理, 结构调控, 聚丙烯的规整结构, 结构和性能关联

While the metallocene catalysts were widely used to produce the metallocene polypropylenes (mPP) in other countries, the traditional Ziegler-Natta catalyst has still been dominantly employed for manufacturing the polypropylenes (PP) in our country at current time. The property of the mPP appears more improved than that of the PP produced by the Ziegler-Natta catalyst, and the market demand for the mPP is worldwidely increasing every year. Therefore, it is urgent to develop the metallocene catalysts for the industrial use in domestic companies. The metallocene catalysts are of versatile structures, which are able to show more exact control over the propylene polymerization activity and the polypropylene stereostructures than the Ziegler-Natta catalyst, and thus catalyze to generate new PPs of the diverse structures. This manuscript will give a detailed summary on the metallocene catalysts so far reported. The important factors such as temperature, propylene pressure, catalyst concentration, cocatalyst types and so on will be illustrated, which all have significant influence on the catalytic reaction activity. The reaction mechanism will be discussed as well.

Key words: metallocene catalyst, propylene polymerization, reaction mechanism, structural control, stereostructure of the polypropylenes, structure and property correalation

引用此文

陈志康, 毛远洪, 曹育才, 梁胜彪, 宋莎, 倪晨, 刘振宇, 叶晓峰, 沈安, 朱红平. 茂金属催化剂体系及其丙烯聚合性能调控[J]. 有机化学, 2018, 38(11): 2937-2992.

Chen Zhikang, Mao Yuanhong, Cao Yucai, Liang Shengbiao, Song Sha, Ni Chen, Liu Zhenyu, Ye Xiaofeng, Shen An, Zhu Hongping. Metallocene Catalyst Systems and Control over the Propylene Polymerization[J]. Chin. J. Org. Chem., 2018, 38(11): 2937-2992.

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茂金属催化剂体系及其丙烯聚合性能调控

Metallocene Catalyst Systems and Control over the Propylene Polymerization

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