f区金属-芳烃相互作用

doi:10.6023/cjoc202405017

摘要/Abstract

近年来, 金属-芳烃相互作用对于推动f区元素配位化学的发展起到了关键作用. 一方面, f区金属芳烃配合物呈现出结构上的多样性, 并主要表现出低价金属合成子的反应性; 另一方面, 在配体设计中引入金属-芳烃相互作用对稳定f区元素的非寻常氧化态和支撑f区元素氧化还原化学发挥了关键作用. 此文回顾了f区金属-芳烃相互作用的发展历史, 综述了近二十年来代表性的f区金属芳烃配合物的合成及反应性, 并对该领域未来的发展作了展望.

关键词: f区元素, 金属-芳烃相互作用, 合成, 结构, 反应性

Recently, metal-arene interactions have played a key role in the advancement of coordination chemistry of f-ele- ments. On the one hand, f-block metal arene complexes with various structural features have been synthesized and characterized, and mainly behave as low-valent metal synthons in reactivity. On the other hand, incorporation of intramolecular metal-arene interactions in ligand design has played a key role in supporting unusual oxidation states and redox chemistry of f-elements. The recent advancement of f-block metal-arene interactions is summarized, including the synthesis and reactivity of representative f-block metal arene complexes, and an outlook on the future development of the field is provided.

Key words: f-elements, metal-arene interactions, synthesis, structures, reactivity

引用此文

邓翀, 王怡, 黄闻亮. f区金属-芳烃相互作用[J]. 有机化学, 2025, 45(1): 56-85.

Chong Deng, Yi Wang, Wenliang Huang. f-Block Metal-Arene Interactions[J]. Chinese Journal of Organic Chemistry, 2025, 45(1): 56-85.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 36

图1-1. (a)稀土和(b)铀的反三明治型芳烃配合物, 以及(c)茂基和(d)酮亚胺基配体支撑的反三明治型f区金属芳烃配合物

Figure 1-1. Inverse-sandwich metal arene complexes of (a) rare-earth metals and (b) uranium, and inverse-sandwich f-block metal arene complexes supported by (c) cyclopentadienyl and (d) ketimide ligands

图1-2. 卡宾衍生物(a)和二茂铁二胺基配体(b)支撑的反三明治型f区金属芳烃配合物

Figure 1-2. Inverse-sandwich f-block metal arene complexes supported by (a) carbene derivatives and (b) ferrocene diamide ligands

图1-3. 三胺基配体(a), 硅氧基配体(b~d), 二硅胺基/酚基/硼氧基配体(e~f)支撑的反三明治型f区金属-芳烃配合物

Figure 1-3. Inverse-sandwich f-block metal arene complexes supported by (a) tris(amide) ligand, (b~d) siloxide ligand, or (e~f) disilylamide/aryloxide/boryloxide ligand

图式1. 含有反三明治型结构单元的多核铀钯簇1.62的合成

Scheme 1. Synthesis of the multinuclear uranium-palladium cluster 1.62 featuring an inverse-sandwich structural unit

图1-4. 代表性的反三明治型稀土芳烃配合物的桥连芳烃结构特征

Figure 1-4. Structural features of the bridging arenes in representative inverse-sandwich rare-earth metal arene complexes

图1-5. 反三明治型铀芳烃配合物的三种典型电子结构

Figure 1-5. Three typical electronic structures of inverse-san- dwich uranium arene complexes

图1-6. 反三明治型f区金属芳烃配合物与原子或基团转移试剂的反应产物

Figure 1-6. Products of the reactions between inverse-sandwich f-block metal arene complexes and atom- or group-transfer reagents

图1-7. 反三明治型f区金属芳烃配合物与不饱和烃的反应产物

Figure 1-7. Products of the reactions between inverse-sandwich f-block metal arene complexes and unsaturated hydrocarbons

图1-8. 反三明治型f区金属芳烃配合物与含磷、砷分子的反应产物

Figure 1-8. Products of the reactions between inverse-sandwich f-block metal arene complexes and P- or As-containing molecules

图2-1. [(R,RArO)3mes]U的合成与反应性

Figure 2-1. Synthesis and reactivity of [(R,RArO)3mes]U

图2-2. 2.3-U介导的电催化分解水

Figure 2-2. Electrocatalytic water splitting mediated by 2.3-U (a) Process, (b) mechanism, (c) independent synthesis of an intermediate

图2-3. [(Ad,MeArO)3mes]3－支撑的稀土配合物

Figure 2-3. Rare-earth metal complexes supported by [(Ad,MeArO)3mes]3－ (a) Reduction chemistry, (b) mechanism of electrocatalytic water splitting, (c) representative structures of Nd(Ⅲ) intermediates

图2-4. (a) [(Ad,MeArS)3mes]3－和(b) [(Me,MeArO3)3benz]3－支撑的锕系金属配合物

Figure 2-4. Actinide complexes supported by (a) [(Ad,MeArS)3mes]3－ and (b) [(Me,MeArO3)3benz]3－

图2-5. (ArTPBN3)3－支撑的稀土配合物的合成与H3(DippTPBN3)单晶结构(35%热椭球图, 氢省略)

Figure 2-5. Synthesis of rare earth metal complexes supported by (ArTPBN3)3－ and the single crystal structure of H3(DippTPBN3) (35% thermal ellipsoid with hydrogen omitted)

图2-6. H3(AdTPBN3)单晶结构(35%热椭球图, 碳上氢原子已省略)

Figure 2-6. Single crystal structure of H3(AdTPBN3) (35% thermal ellipsoid with CH atoms omitted)

图2-7. (AdTPBN3)3−支撑的铀配合物的氧化还原转化

Figure 2-7. Redox transformation of uranium complexes supported by (AdTPBN3)3−

Compound	2.19-U^a	2.18-U	2.20-UF/2.20-UI	2.22-U	2.21	2.23
Oxidation state of uranium	Ⅱ	Ⅲ	Ⅳ	Ⅳ	Ⅴ	Ⅵ
U—N/Å^b	2.477(3)	2.423(2)	2.323(2)/2.293(3)	2.421(4)	2.317(3)	2.274(3)
U—Cnt/Å	2.18	2.34	2.53/2.63	2.69	2.57	2.49
U—C/Å^b	2.596(4)	2.703(3)	2.893(3)/2.981(4)	3.028(4)	2.922(3)	2.860(4)
U—3N_plane/Å^c	－0.34	－0.17	0.07/0.11	0.25	0.12	0.04
U—X/Å	—	—	2.090(2)/3.085(1)	1.874(4)	1.829(2)	1.818(2)

表1. (AdTPBN3)3−支撑的铀(Ⅱ~Ⅵ)配合物的关键结构数据

Table 1. Key structural parameters of uranium(Ⅱ~Ⅵ) complexes supported by (AdTPBN3)3−

图2-8. (a) 2.18-Ce的单电子氧化还原过程和(b)稀土(铈)的单中心两电子氧化

Figure 2-8. (a) One-electron redox processes of 2.18-Ce, and (b) single-center-two-electron oxidations for rare earth (cerium)

图2-9. (RTPBN3)3－ (R=Ad, Dtbp)支撑的钍配合物的还原化学

Figure 2-9. Reduction chemistry of thorium complexes supported by (RTPBN3)3－ (R=Ad, Dtbp)

图2-10. [(OSi(OtBu)2Ar)3-arene]3－支撑的铈配合物的合成及其反应化学

Figure 2-10. Synthesis and reactivity of cerium complexes supported by [(OSi(OtBu)2Ar)3-arene]3－

图2-11. [(OSi(Ph)2Ar)3-arene]3－支撑的稀土配合物的合成

Figure 2-11. Synthesis of rare earth metal complexes supported by [(OSi(Ph)2Ar)3-arene]3－

图2-12. [(OSi(OtBu)2Ar)3-arene]3－支撑的铀配合物的合成

Figure 2-12. Synthesis of uranium complexes supported by [(OSi(OtBu)2Ar)3-arene]3－

图2-13. 2.34, 2.43 (三聚体的1/3), 2.49'的单晶结构(35%热椭球图, 氢省略)

Figure 2-13. Single crystal structures of 2.34, 2.43 (1/3 of the trimer), 2.49' (35% thermal ellipsoid with hydrogen omitted)

图2-14. [(OSi(R)2Ar)3-arene]3－ (R=OtBu, Ph)支撑的钍配合物的合成与反应性

Figure 2-14. Synthesis and reactivity of thorium complexes supported by [(OSi(R)2Ar)3-arene]3－ (R=OtBu, Ph)

图3-1. 单负离子配体以金属-芳烃相互作用为桥形成的多核f区金属配合物

Figure 3-1. Multi-nuclear f-block metal complexes supported by monoanionic ligands with metal-arene interaction

图3-2. 存在金属-芳烃相互作用的单负离子配体支撑的单核f区金属配合物

Figure 3-2. Mononuclear f-block metal complexes supported by monoanionic ligands featuring metal-arene interactions

图3-3. [NHDppiPr6]－支撑的铀和钇配合物的合成

Figure 3-3. Synthesis of uranium and yttrium complexes supported by [NHDppiPr6]－

图3-4. 存在金属-芳烃相互作用的二价镧系金属脒基、胍基、三嗪基配合物

Figure 3-4. Divalent lanthanide amidinato, guanidinato, triazenido complexes featuring metal-arene interactions

图3-5. [tBuCONDipp]－支撑的(a)铀和(b)钍配合物

Figure 3-5. (a) Uranium and (b) thorium complexes supported by [tBuCONDipp]－

图3-6. 芳烃锚定的二烯胺配体支撑的铀(Ⅲ)配合物的还原化学

Figure 3-6. Reduction chemistry of the uranium(Ⅲ) complex supported by an arene-tethered bis(enamino) ligand

图3-7. 芳烃锚定二吡咯基配体支撑的钍(Ⅳ)配合物的还原化学 Reduction chemistry of the thorium(Ⅳ) complex supported by an arene-tethered bis(pyrrolide) ligand

Figure 3-7.

图3-8. 二苯二吡咯配体支撑的f区金属配合物的合成

Figure 3-8. Synthesis of f-block metal complexes supported by the bis(benzene)-bis(pyrrolide) ligand (a) Samarium, (b) thorium, (c) uranium, (d) neptunium

图3-9. 对三联苯二芳胺配体支撑的三价f区金属配合物的合成

Figure 3-9. Synthesis of trivalent f-block metal complexes supported by a p-terphenyl bis(aniline) ligand

图3-10. 对三联苯二芳胺基配体支撑的铀配合物的反应性

Figure 3-10. Reactivity of uranium complexes supported by a p-terphenyl bis(aniline) ligand

图3-11. 对二甲苯锚定四酚基配体支撑的铀和钍配合物

Figure 3-11. Uranium and thorium complexes supported by the p-xylene tethered tetraphenolate ligand

图3-12. 3.67-Gd的单晶结构(35%热椭球图, 氢和抗衡阳离子省略)

Figure 3-12. Single crystal structure of 3.67-Gd (35% thermal ellipsoid with hydrogen and counter cations omitted)

参考文献 127

[1]	Spessard, G. O.; Miessler, G. L. Organometallic Chemistry (3rd edition), Oxford University Press, Oxford, 2015.
[2]	Cesari, M.; Pedretti, U.; Zazzetta, A.; Lugli, G.; Marconi, W. Inorg. Chim. Acta 1971, 5, 439.
[3]	Cotton, F. A.; Schwotzer, W. J. Am. Chem. Soc. 1986, 108, 4657.
[4]	Deacon, G. B.; Shen, Q. J. Organomet. Chem. 1996, 506, 1.
[5]	Bochkarev, M. N. Chem. Rev. 2002, 102, 2089.
[6]	Roy Chowdhury, S.; A. P. Goodwin, C.; Vlaisavljevich, B. Chem. Sci. 2024, 15, 1810.
[7]	Cloke, F. G. N. Chem. Soc. Rev. 1993, 22, 17.
[8]	Cassani, M. C.; Duncalf, D. J.; Lappert, M. F. J. Am. Chem. Soc. 1998, 120, 12958.
[9]	Diaconescu, P. L.; Arnold, P. L.; Baker, T. A.; Mindiola, D. J.; Cummins, C. C. J. Am. Chem. Soc. 2000, 122, 6108.
[10]	Cloke, F. G. N.; Tsoureas, N. In Comprehensive Organometallic Chemistry IV, Eds.: Parkin, G.; Meyer, K.; O'hare, D., Elsevier, Amsterdam, 2022, pp. 405-459.
[11]	Cryer, J. D.; Liddle, S. T. In Comprehensive Organometallic Chemistry IV, Eds.: Parkin, G.; Meyer, K.; O'hare, D., Elsevier, Amsterdam, 2022, pp. 460-501.
[12]	Liddle, S. T. Coord. Chem. Rev. 2015, 293-294, 211.
[13]	La Pierre, H. S.; Scheurer, A.; Heinemann, F. W.; Hieringer, W.; Meyer, K. Angew. Chem., Int. Ed. 2014, 53, 7158.
[14]	Deng, C.; Huang, W.; Su, Y. J. Nucl. Radiochem. 2021, 43, 1 (in Chinese)
	(邓翀, 黄闻亮, 苏一茂, 核化学与放射化学, 2021, 43, 1.)
[15]	Wang, Y.; Huang, W. Sci. Sin.: Chim. 2020, 50, 1504.
[16]	Halter, D. P.; Heinemann, F. W.; Bachmann, J.; Meyer, K. Nature 2016, 530, 317.
[17]	Halter, D. P.; Heinemann, F. W.; Maron, L.; Meyer, K. Nat. Chem. 2018, 10, 259.
[18]	Halter, D. P.; Palumbo, C. T.; Ziller, J. W.; Gembicky, M.; Rheingold, A. L.; Evans, W. J.; Meyer, K. J. Am. Chem. Soc. 2018, 140, 2587.
[19]	Hartline, D. R.; Meyer, K. JACS Au 2021, 1, 698.
[20]	Fryzuk, M. D.; Love, J. B.; Rettig, S. J. J. Am. Chem. Soc. 1997, 119, 9071.
[21]	Gun'ko, Y. K.; Hitchcock, P. B.; Lappert, M. F. Organometallics 2000, 19, 2832.
[22]	Palumbo, C. T.; Darago, L. E.; Dumas, M. T.; Ziller, J. W.; Long, J. R.; Evans, W. J. Organometallics 2018, 37, 3322.
[23]	Cassani, M. C.; Gun'ko, Y. K.; Hitchcock, P. B.; Lappert, M. F. Chem. Commun. 1996, 1996, 1987.
[24]	Kotyk, C. M.; Fieser, M. E.; Palumbo, C. T.; Ziller, J. W.; Darago, L. E.; Long, J. R.; Furche, F.; Evans, W. J. Chem. Sci. 2015, 6, 7267.
[25]	Reinfandt, N.; Michenfelder, N.; Schoo, C.; Yadav, R.; Reichl, S.; Konchenko, S. N.; Unterreiner, A. N.; Scheer, M.; Roesky, P. W. Chem.-Eur. J. 2021, 27, 7862.
[26]	Diaconescu, P. L.; Cummins, C. C. J. Am. Chem. Soc. 2002, 124, 7660.
[27]	Diaconescu, P. L.; Cummins, C. C. Inorg. Chem. 2012, 51, 2902.
[28]	Evans, W. J.; Kozimor, S. A.; Ziller, J. W.; Kaltsoyannis, N. J. Am. Chem. Soc. 2004, 126, 14533.
[29]	Evans, W. J.; Traina, C. A.; Ziller, J. W. J. Am. Chem. Soc. 2009, 131, 17473.
[30]	Mills, D. P.; Moro, F.; McMaster, J.; van Slageren, J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Nat. Chem. 2011, 3, 454.
[31]	Wooles, A. J.; Mills, D. P.; Tuna, F.; McInnes, E. J. L.; Law, G. T. W.; Fuller, A. J.; Kremer, F.; Ridgway, M.; Lewis, W.; Gagliardi, L.; Vlaisavljevich, B.; Liddle, S. T. Nat. Commun. 2018, 9, 2097.
[32]	Monreal, M. J.; Khan, S. I.; Kiplinger, J. L.; Diaconescu, P. L. Chem. Commun. 2011, 47, 9119.
[33]	Huang, W.; Dulong, F.; Wu, T.; Khan, S. I.; Miller, J. T.; Cantat, T.; Diaconescu, P. L. Nat. Commun. 2013, 4, 1448.
[34]	Huang, W.; Le Roy, J. J.; Khan, S. I.; Ungur, L.; Murugesu, M.; Diaconescu, P. L. Inorg. Chem. 2015, 54, 2374.
[35]	Xiao, Y.; Zhao, X.-K.; Wu, T.; Miller, J. T.; Hu, H.-S.; Li, J.; Huang, W.; Diaconescu, P. L. Chem. Sci. 2021, 12, 227.
[36]	Patel, D.; Moro, F.; McMaster, J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Angew. Chem., Int. Ed. 2011, 50, 10388.
[37]	Patel, D.; Tuna, F.; McInnes, E. J. L.; McMaster, J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Dalton Trans. 2013, 42, 5224.
[38]	Mougel, V.; Camp, C.; Pécaut, J.; Copéret, C.; Maron, L.; Kefalidis, C. E.; Mazzanti, M. Angew. Chem., Int. Ed. 2012, 51, 12280.
[39]	Camp, C.; Mougel, V.; Pécaut, J.; Maron, L.; Mazzanti, M. Chem.- Eur. J. 2013, 19, 17528.
[40]	Kelly, R. P.; Maron, L.; Scopelliti, R.; Mazzanti, M. Angew. Chem., Int. Ed. 2017, 56, 15663.
[41]	Kelly, R. P.; Toniolo, D.; Tirani, F. F.; Maron, L.; Mazzanti, M. Chem. Commun. 2018, 54, 10268.
[42]	Arnold, P. L.; Mansell, S. M.; Maron, L.; McKay, D. Nat. Chem. 2012, 4, 668.
[43]	Arnold, P. L.; Halliday, C. J. V.; Puig-Urrea, L.; Nichol, G. S. Inorg. Chem. 2021, 60, 4162.
[44]	Yu, C.; Liang, J.; Deng, C.; Lefèvre, G.; Cantat, T.; Diaconescu, P. L.; Huang, W. J. Am. Chem. Soc. 2020, 142, 21292.
[45]	Hsueh, F.-C.; Rajeshkumar, T.; Kooij, B.; Scopelliti, R.; Severin, K.; Maron, L.; Zivkovic, I.; Mazzanti, M. Angew. Chem., Int. Ed. 2023, 62, e202215846.
[46]	Deng, C.; Xu, X.-C.; Sun, R.; Wang, Y.; Wang, B.-W.; Hu, H.-S.; Huang, W. Organometallics 2024, 43, 174.
[47]	Fang, W.; Li, Y.; Zhang, T.; Rajeshkumar, T.; del Rosal, I.; Zhao, Y.; Wang, T.; Wang, S.; Maron, L.; Zhu, C. Angew. Chem., Int. Ed. 2024, 63, e202407339.
[48]	Vlaisavljevich, B.; Diaconescu, P. L.; Lukens, W. L.; Gagliardi, L.; Cummins, C. C. Organometallics 2013, 32, 1341.
[49]	Wooles, A. J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Organometallics 2013, 32, 5058.
[50]	Yamamoto, K.; Sugawa, T.; Murahashi, T. Coord. Chem. Rev. 2022, 466, 214575.
[51]	Evans, W. J.; Kozimor, S. A.; Ziller, J. W. Chem. Commun. 2005, 4681.
[52]	Patel, D.; Tuna, F.; McInnes, E. J. L.; Lewis, W.; Blake, A. J.; Liddle, S. T. Angew. Chem., Int. Ed. 2013, 52, 13334.
[53]	Reinfandt, N.; Hauser, A.; Münzfeld, L.; Roesky, P. W. Chem. Sci. 2022, 13, 3363.
[54]	Bart, S. C.; Heinemann, F. W.; Anthon, C.; Hauser, C.; Meyer, K. Inorg. Chem. 2009, 48, 9419.
[55]	Lam, O. P.; Bart, S. C.; Kameo, H.; Heinemann, F. W.; Meyer, K. Chem. Commun. 2010, 46, 3137.
[56]	Castro, L.; Lam, O. P.; Bart, S. C.; Meyer, K.; Maron, L. Organometallics 2010, 29, 5504.
[57]	La Pierre, H. S.; Kameo, H.; Halter, D. P.; Heinemann, F. W.; Meyer, K. Angew. Chem., Int. Ed. 2014, 53, 7154.
[58]	MacDonald, M. R.; Fieser, M. E.; Bates, J. E.; Ziller, J. W.; Furche, F.; Evans, W. J. J. Am. Chem. Soc. 2013, 135, 13310.
[59]	Halter, D. P.; La Pierre, H. S.; Heinemann, F. W.; Meyer, K. Inorg. Chem. 2014, 53, 8418.
[60]	Fieser, M. E.; Palumbo, C. T.; La Pierre, H. S.; Halter, D. P.; Voora, V. K.; Ziller, J. W.; Furche, F.; Meyer, K.; Evans, W. J. Chem. Sci. 2017, 8, 7424.
[61]	MacDonald, M. R.; Bates, J. E.; Ziller, J. W.; Furche, F.; Evans, W. J. J. Am. Chem. Soc. 2013, 135, 9857.
[62]	Palumbo, C. T.; Halter, D. P.; Voora, V. K.; Chen, G. P.; Chan, A. K.; Fieser, M. E.; Ziller, J. W.; Hieringer, W.; Furche, F.; Meyer, K.; Evans, W. J. Inorg. Chem. 2018, 57, 2823.
[63]	Palumbo, C. T.; Halter, D. P.; Voora, V. K.; Chen, G. P.; Ziller, J. W.; Gembicky, M.; Rheingold, A. L.; Furche, F.; Meyer, K.; Evans, W. J. Inorg. Chem. 2018, 57, 12876.
[64]	Fieser, M. E.; MacDonald, M. R.; Krull, B. T.; Bates, J. E.; Ziller, J. W.; Furche, F.; Evans, W. J. J. Am. Chem. Soc. 2015, 137, 369.
[65]	Pividori, D.; Miehlich, M. E.; Kestel, B.; Heinemann, F. W.; Scheurer, A.; Patzschke, M.; Meyer, K. Inorg. Chem. 2021, 60, 16455.
[66]	Yang, Z.-C.; Cai, H.-X.; Bacha, R. U. S.; Ding, S.-D.; Pan, Q.-J. Inorg. Chem. 2022, 61, 11715.
[67]	Xin, T.; Wang, X.; Yang, K.; Liang, J.; Huang, W. Inorg. Chem. 2021, 60, 15321.
[68]	Deacon, G. B.; Feng, T.; Forsyth, C. M.; Gitlits, A.; Hockless, D. C. R.; Shen, Q.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 2000, 2000, 961.
[69]	Deng, C.; Liang, J.; Sun, R.; Wang, Y.; Fu, P.-X.; Wang, B.-W.; Gao, S.; Huang, W. Nat. Commun. 2023, 14, 4657.
[70]	Wang, Y.; Liang, J.; Deng, C.; Sun, R.; Fu, P.-X.; Wang, B.-W.; Gao, S.; Huang, W. J. Am. Chem. Soc. 2023, 145, 22466.
[71]	Assefa, M. K.; Wu, G.; Hayton, T. W. Chem. Sci. 2017, 8, 7873.
[72]	Dutkiewicz, M. S.; Goodwin, C. A. P.; Perfetti, M.; Gaunt, A. J.; Griveau, J.-C.; Colineau, E.; Kovács, A.; Wooles, A. J.; Caciuffo, R.; Walter, O.; Liddle, S. T. Nat. Chem. 2022, 14, 342.
[73]	Deng, C.; Liang, J.; Wang, Y.; Huang, W. Inorg. Chem. 2024, 63, 9676.
[74]	Hsueh, F.-C.; Rajeshkumar, T.; Maron, L.; Scopelliti, R.; Sienkiewicz, A.; Mazzanti, M. Chem. Sci. 2023, 14, 6011.
[75]	Hillenbrand, J.; Leutzsch, M.; Fürstner, A. Angew. Chem., Int. Ed. 2019, 58, 15690.
[76]	Guo, H.; Hong, D.; Cui, P. Dalton Trans. 2023, 52, 15672.
[77]	Tricoire, M.; Hsueh, F.-C.; Keener, M.; Rajeshkumar, T.; Scopelliti, R.; Zivkovic, I.; Maron, L.; Mazzanti, M. Chem. Sci. 2024, 15, 6874.
[78]	Keener, M.; Shivaraam, R. A. K.; Rajeshkumar, T.; Tricoire, M.; Scopelliti, R.; Zivkovic, I.; Chauvin, A.-S.; Maron, L.; Mazzanti, M. J. Am. Chem. Soc. 2023, 145, 16271.
[79]	Hsueh, F.-C.; Chen, D.; Rajeshkumar, T.; Scopelliti, R.; Maron, L.; Mazzanti, M. Angew. Chem., Int. Ed. 2023, 63, e202317346.
[80]	Cruz, C. A.; Emslie, D. J. H.; Robertson, C. M.; Harrington, L. E.; Jenkins, H. A.; Britten, J. F. Organometallics 2009, 28, 1891.
[81]	Wedal, J. C.; Barlow, J. M.; Ziller, J. W.; Yang, J. Y.; Evans, W. J. Chem. Sci. 2021, 12, 8501.
[82]	Van der Sluys, W. G.; Burns, C. J.; Huffman, J. C.; Sattelberger, A. P. J. Am. Chem. Soc. 1988, 110, 5924.
[83]	Barnhart, D. M.; Clark, D. L.; Gordon, J. C.; Huffman, J. C.; Vincent, R. L.; Watkin, J. G.; Zwick, B. D. Inorg. Chem. 1994, 33, 3487.
[84]	Butcher, R. J.; Clark, D. L.; Grumbine, S. K.; Vincent-Hollis, R. L.; Scott, B. L.; Watkin, J. G. Inorg. Chem. 1995, 34, 5468.
[85]	Boyle, T. J.; Bunge, S. D.; Clem, P. G.; Richardson, J.; Dawley, J. T.; Ottley, L. A. M.; Rodriguez, M. A.; Tuttle, B. A.; Avilucea, G. R.; Tissot, R. G. Inorg. Chem. 2005, 44, 1588.
[86]	Boyle, T. J.; Ottley, L. A. M.; Brewer, L. N.; Sigman, J.; Clem, P. G.; Richardson, J. J. Eur. J. Inorg. Chem. 2007, 2007, 3805.
[87]	Evans, W. J.; Ansari, M. A.; Ziller, J. W.; Khan, S. I. Inorg. Chem. 1996, 35, 5435.
[88]	Gordon, J. C.; Giesbrecht, G. R.; Clark, D. L.; Hay, P. J.; Keogh, D. W.; Poli, R.; Scott, B. L.; Watkin, J. G. Organometallics 2002, 21, 4726.
[89]	Giesbrecht, G. R.; Gordon, J. C.; Clark, D. L.; Hay, P. J.; Scott, B. L.; Tait, C. D. J. Am. Chem. Soc. 2004, 126, 6387.
[90]	Wang, Y.; Del Rosal, I.; Qin, G.; Zhao, L.; Maron, L.; Shi, X.; Cheng, J. Chem. Commun. 2021, 57, 7766.
[91]	Keerthi Shivaraam, R. A.; Keener, M.; Modder, D. K.; Rajeshkumar, T.; Živković, I.; Scopelliti, R.; Maron, L.; Mazzanti, M. Angew. Chem., Int. Ed. 2023, 62, e202304051.
[92]	Deacon, G.; Nickel, S.; Mackinnon, P.; Tiekink, E. Aust. J. Chem. 1990, 43, 1245.
[93]	Deacon, G.; Feng, T.; Skelton, B.; White, A. Aust. J. Chem. 1995, 48, 741.
[94]	McKinven, J.; Nichol, G. S.; Arnold, P. L. Dalton Trans. 2014, 43, 17416.
[95]	Meng, Y.-S.; Xu, L.; Xiong, J.; Yuan, Q.; Liu, T.; Wang, B.-W.; Gao, S. Angew. Chem., Int. Ed. 2018, 57, 4673.
[96]	Cole, M. L.; Deacon, G. B.; Junk, P. C.; Proctor, K. M.; Scott, J. L.; Strauss, C. R. Eur. J. Inorg. Chem. 2005, 2005, 4138.
[97]	Niemeyer, M. Eur. J. Inorg. Chem. 2001, 2001, 1969.
[98]	Cofone, A.; Niemeyer, M. Z. Anorg. Allg. Chem. 2006, 632, 1930.
[99]	Hauber, S.-O.; Niemeyer, M. Chem. Commun. 2007, 2007, 275.
[100]	Gilbert-Bass, K.; Stennett, C. R.; Grotjahn, R.; Ziller, J. W.; Furche, F.; Evans, W. J. Chem. Commun. 2024, 60, 4601.
[101]	Billow, B. S.; Livesay, B. N.; Mokhtarzadeh, C. C.; McCracken, J.; Shores, M. P.; Boncella, J. M.; Odom, A. L. J. Am. Chem. Soc. 2018, 140, 17369.
[102]	Wedal, J. C.; Furche, F.; Evans, W. J. Inorg. Chem. 2021, 60, 16316.
[103]	Jena, R.; Benner, F.; Delano, F.; Holmes, D.; McCracken, J.; Demir, S.; Odom, A. L. Chem. Sci. 2023, 14, 4257.
[104]	Reinhart, E. D.; Studvick, C. M.; Tondreau, A. M.; Popov, I. A.; Boncella, J. M. Organometallics 2024, 43, 284.
[105]	Heitmann, D.; Jones, C.; Mills, D. P.; Stasch, A. Dalton Trans. 2010, 39, 1877.
[106]	Heitmann, D.; Jones, C.; Junk, P. C.; Lippert, K.-A.; Stasch, A. Dalton Trans. 2007, 2007, 187.
[107]	Hauber, S.-O.; Niemeyer, M. Inorg. Chem. 2005, 44, 8644.
[108]	Basalov, I. V.; Lyubov, D. M.; Fukin, G. K.; Shavyrin, A. S.; Trifonov, A. A. Angew. Chem., Int. Ed. 2012, 51, 3444.
[109]	Basalov, I. V.; Yurova, O. S.; Cherkasov, A. V.; Fukin, G. K.; Trifonov, A. A. Inorg. Chem. 2016, 55, 1236.
[110]	Basalov, I. V.; Lyubov, D. M.; Fukin, G. K.; Cherkasov, A. V.; Trifonov, A. A. Organometallics 2013, 32, 1507.
[111]	Lyubov, D. M.; Basalov, I. V.; Shavyrin, A. S.; Cherkasov, A. V.; Trifonov, A. A. Russ. J. Coord. Chem. 2019, 45, 728.
[112]	Straub, M. D.; Ouellette, E. T.; Boreen, M. A.; Britt, R. D.; Chakarawet, K.; Douair, I.; Gould, C. A.; Maron, L.; Del Rosal, I.; Villarreal, D.; Minasian, S. G.; Arnold, J. J. Am. Chem. Soc. 2021, 143, 19748.
[113]	Korobkov, I.; Gorelsky, S.; Gambarotta, S. J. Am. Chem. Soc. 2009, 131, 10406.
[114]	Korobkov, I.; Vidjayacoumar, B.; Gorelsky, S. I.; Billone, P.; Gambarotta, S. Organometallics 2010, 29, 692.
[115]	Ilango, S.; Vidjayacoumar, B.; Gambarotta, S. Dalton Trans. 2010, 39, 6853.
[116]	Arnold, P. L.; Farnaby, J. H.; White, R. C.; Kaltsoyannis, N.; Gardiner, M. G.; Love, J. B. Chem. Sci. 2014, 5, 756.
[117]	Suvova, M.; O’Brien, K. T. P.; Farnaby, J. H.; Love, J. B.; Kaltsoyannis, N.; Arnold, P. L. Organometallics 2017, 36, 4669.
[118]	Arnold, P. L.; Stevens, C. J.; Farnaby, J. H.; Gardiner, M. G.; Nichol, G. S.; Love, J. B. J. Am. Chem. Soc. 2014, 136, 10218.
[119]	Arnold, P. L.; Farnaby, J. H.; Gardiner, M. G.; Love, J. B. Organometallics 2015, 34, 2114.
[120]	Dutkiewicz, M. S.; Farnaby, J. H.; Apostolidis, C.; Colineau, E.; Walter, O.; Magnani, N.; Gardiner, M. G.; Love, J. B.; Kaltsoyannis, N.; Caciuffo, R.; Arnold, P. L. Nat. Chem. 2016, 8, 797.
[121]	Fortier, S.; Aguilar-Calderón, J. R.; Vlaisavljevich, B.; Metta-Magaña, A. J.; Goos, A. G.; Botez, C. E. Organometallics 2017, 36, 4591.
[122]	Harriman, K. L. M.; Murillo, J.; Suturina, E. A.; Fortier, S.; Murugesu, M. Inorg. Chem. Front. 2020, 7, 4805.
[123]	Gaunt, A.; Murillo, J.; Goodwin, C. A. P.; Stevens, L.; Fortier, S.; Scott, B. Chem. Sci. 2023, 14, 7438.
[124]	Inman, C. J.; Frey, A. S. P.; Kilpatrick, A. F. R.; Cloke, F. G. N.; Roe, S. M. Organometallics 2017, 36, 4539.
[125]	Yadav, M.; Metta-Magaña, A.; Fortier, S. Chem. Sci. 2020, 11, 2381.
[126]	Lam, F. Y. T.; Wells, J. A. L.; Ochiai, T.; Halliday, C. J. V.; McCabe, K. N.; Maron, L.; Arnold, P. L. Inorg. Chem. 2022, 61, 4581.
[127]	Gould, C. A.; Marbey, J.; Vieru, V.; Marchiori, D. A.; David Britt, R.; Chibotaru, L. F.; Hill, S.; Long, J. R. Nat. Chem. 2021, 13, 1001