有机化学 ›› 1983, Vol. 3 ›› Issue (5): 345-352. 上一篇    下一篇

研究论文

甲基冠醚的合成

胡宏纹;陆国元   

  1. 南京大学化学系
  • 发布日期:1983-10-25

Synthesis of crown ethers with methyl groups

HU HONGWEN;LU GUOYUAN   

  • Published:1983-10-25

关键词: 甲基, 冠式化合物, 醚, 丙二醇 P, 乙二醇醚 P, 丙烯醇 P

Allyl ethers (1,2,3) were mercurated in \B\-chloroethyl alcohol and then demercurated by KBH4 to give dichlorides with methyl groups (5,6,7). The dichlorides were further condensed with satechol in the presence of potassium hydroxide to give the corresponding crown ethers.

Key words: METHYL GROUP, CROWN ETHER COMPOUNDS, ETHER, PROPANEDIOL P, ETHYLENE GLYCOL ETHER P, PROPENOL P

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