关键词: 二异丙基芳酰甲酰胺, 环加成反应, 不对称反应, 二苯并桶烯二羧酸二异丙酯, 河南省杰出青年基金, 甲基金刚烷基氯苯乙酮

The formation of enantiopure optically active biomolecules is an important chapter in the history of evolution. "Absolute" asymmetric synthesis, i. e. an asymmetric synthesis carried out in a closed system without any external chiral inducing agents or with circularly polarized light, supports the explanations of how optical activity could have arisen under pre-biotic conditions. In the present review, we describe the asymmetric synthesis via the reactions of chiral crystals of achiral molecules.

Key words: CYCLOADDITION REACTION