有机化学 ›› 1997, Vol. 17 ›› Issue (2): 142-148. 上一篇    下一篇

研究论文

改进的Ugi法应用于胺烷基二茂铁衍生物的合成

江焕峰;张伦   

  1. 中国科学院广州化学研究所;武汉大学化学系
  • 发布日期:1997-04-25

Studies on the synthesis of aminoalkyl ferrocence derivatives via improved Ugi reaction

JIANG HUANFENG;ZHANG LUN   

  • Published:1997-04-25

选择不同的按或酰胺组分, 利用改进的Ugi法合成了一系歹含有烷胺烷基、芳胺烷基或酰胺烷基的二茂铁衍生物, 研究了反应的投料比, 反应底物, 反应温域等因素对反应的影响, 并对反应机理进行了探讨。

关键词: 二茂铁 P, 酰胺, 红外分光光度法, 胺, 影响因素, 反应机理

Some amines or amides were employed for the synthesis of several aminoalkyl-substituted ferrocence dervatives via improved Ugi reaction. The effects of various factors, such as ratio of reactants, structure of the substrates and reaction temperature were studied, and a reaction mechanism was preposed.

Key words: AMINES, FERROCENE P, INFRARED SPECTROPHOTOMETRY, INFLUENCING FACTORS, REACTION MECHANISM, AMIDES

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