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有机化学
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有机化学 ›› 1999, Vol. 19 ›› Issue (1): 15-26. 上一篇    下一篇

研究论文

全(多)氟酰基过氧化物的化学及应用

赵成学;曲延玲;贺海鹰;周志彬   

  1. 上海交通大学化学化工学院
  • 发布日期:1999-02-25

Per(poly)fluorodiacyl peroxides-chemistry and application

Zhao Chengxue;Qu Yanling;He Haiying;Zhou Zhibin   

  • Published:1999-02-25

被引次数

12

综述了含氟新试剂全(多)氟酰基过氧化物的合成、热分解及其与富电子芳香族受物间的单电子转移反应的机理。并简要地介绍了它作为对芳环、芳杂环有效的全氟烷基化试剂及烯烃聚合的引发剂在合成含氟功能化合物领域中的重要应用。

关键词: 过氧化物, 电子转移, 热分解, 应用, 反应机理, 有机氟化合物

The synthesis of per(poly)fluorodiacyl peroxides, the kinetic studies and product analysis of their thermal decomposition, the mechanistic investigation of their electron-transfer reactions with electron-rich aromatics and nitrogen-containing substrates as well as their application as effective aromatic ring-per(poly)fluoro- alkylating agents and initiators of oligomerization of vinyl monomes are reviewed in this paper.

Key words: PEROXIDE, APPLICATION, THERMAL DECOMPOSITION, REACTION MECHANISM, ORGANO FLUORINE COMPOUNDS

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