有机化学 ›› 2003, Vol. 23 ›› Issue (10): 1058-1063. 上一篇    下一篇

研究论文

固态有机合成反应进展

臧洪俊;李正名;王宝雷   

  1. 南开大学元素有机化学研究所
  • 发布日期:2003-10-25

Progress in Solid State Organic Synthesis

Zang Hongjun;Li Zhengming;Wang Baolei   

  1. Institute of Elemento-Organic Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University
  • Published:2003-10-25

以绿色合成为主题,综述了近期固相有机合成研究方面的一些新进展和典型反 应类型。由于固相反应的特征,多数固相有机反应表现出较溶液中更高的反应效率 和更好的选择性,并讨论了固态反应中的分子运动及其固态反应的因素。

关键词: 有机合成, 固相反应, 选择性, 溶液反应

Due to the increasing interests in green chemistry, some recent progresses in certain classical organic reaction in solid state are reviewed in this paper. Most of the solid state organic reactions occur more efficiently and selectively than the corresponding solution reactions, probably because the solid state reactions proceed in very high concentration and highly organized reaction environment. The related mechanism is discussed as well.

Key words: ORGANIC SYNTHESIS, SOLID PHASE REACTION, SELECTIVITY, solution reaction

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