SIOC English
有机化学
高级检索

有机化学 ›› 2004, Vol. 24 ›› Issue (2): 166-168. 上一篇    下一篇

研究论文

α-羰基硫代甲酰胺与溴的反应研究

曾润生a, 邹建平*,a, 支三军b, 沈琪a   

  1. a苏州大学化学系 苏州 215006
    b淮阴师范学院化学系 淮阴 22300
  • 收稿日期:2002-11-07 修回日期:2003-07-15 接受日期:2003-08-20 发布日期:2022-09-20
  • 基金资助:
    江苏省有机合成重点实验室(No. T2109103)和苏州市科委(No. SG 0219)资助项目.

Study on the Reaction of α-Oxothioacetamide with Bromine

ZENG, Run-Shenga, ZOU, Jian-Ping*,a, ZHI, San-Junb, Shen, Qia   

  1. aDepartment of Chemistry, Suzhou University, Suzhou 215006
    bDepartment of Chemistry, Huaiyin Teacher's College, Huaiyin 223000
  • Received:2002-11-07 Revised:2003-07-15 Accepted:2003-08-20 Published:2022-09-20
  • Contact: * E-mail: jpzou@suda.edu.cn

PDF

79

报道了α-羰基硫代甲酰胺与溴在三乙胺存在下的反应,合成了二[(1-芳基亚胺基-1-苯甲酰基)甲基]二硫醚类化合物,产率为60%～65%.它们的结构经元素分析、红外光谱、核磁共振光谱和质谱分析得到确证.

关键词: α-羰基硫代甲酰胺, 二[(1-芳基亚胺基-1-苯甲酰基)甲基]二硫醚, 反应

α-Oxothioacetamide represents a class of stable and little explored compounds. The reaction of α-oxothioacetamide with bromine in the presence of triethylamine was explored, and a new type of compounds called bis~[(1-arylimino-1-benzoyl)methyl] disulfide was obtained in 60%～65% yields and their structures were characterized by IR, NMR, ms spectra and elemental analyses.

Key words: α-oxothioacetamide, bis[(1-arylimino-1-benzoyl)methyl] disulfide, reaction