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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (11): 1334-1341. 上一篇    下一篇

综述与进展

烯烃的交叉复分解反应(CM)及其合成应用

郭盈岑，肖文精*   

  1. (华中师范大学化学学院农药与化学生物学教育部重点实验室 武汉 430079)
  • 收稿日期:2004-11-03 修回日期:2005-03-25 发布日期:2005-10-30
  • 通讯作者: 肖文精

Olefin Cross-metathesis Reactions and Their Applications toOrganic Synthesis

GUO Ying-Cen, XIAO Wen-Jing*   

  1. (Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry,
    Huazhong Normal University, Wuhan 430079)
  • Received:2004-11-03 Revised:2005-03-25 Published:2005-10-30
  • Contact: XIAO Wen-Jing

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4239

被引次数

27 | 3

概述了近年来烯烃交叉复分解反应的研究进展及其在有机中间体制备、碳水化合物的合成、高分子化学以及工业生产上的应用.

关键词: 钌卡宾络合物, 烯烃, 交叉复分解反应, 有机合成

Ruthenium-catalyzed olefin cross-metathesis reaction is one of the most efficient methods for the construction of C＝C bonds. In the past few years, much attention has been paid to their application to the synthesis of fine chemicals, natural products, polychemistry, and industry. In this paper, we summarize the most recent progress of olefin cross-metathesis reactions as well as their applications to organic synthesis.

Key words: cross-metathesis, organic synthesis, olefin, Ru carbene complex