有机化学 ›› 2005, Vol. 25 ›› Issue (11): 1342-1352. 上一篇    下一篇

综述与进展

低价钛在有机合成中的应用新进展

杨忠顺,李英*   

  1. (中国科学院上海药物研究所 上海 201203)
  • 收稿日期:2005-01-10 修回日期:2005-04-10 发布日期:2005-10-30
  • 通讯作者: 李英

Recent Advances on Application of Low Valent Titanium to Organic Synthesis

YANG Zhong-Shun, LI Ying*   

  1. (Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203)
  • Received:2005-01-10 Revised:2005-04-10 Published:2005-10-30
  • Contact: LI Ying

主要综述了近年来低价钛诱导的McMurry反应在有机合成中的应用新进展.

关键词: 低价钛, McMurry反应, 还原偶联, 有机合成

McMurry reaction has displayed much significance in organic synthesis since it was discovered in 1970’s. Recent developments on application of low valent titanium to organic synthesis including those of (non)natural products and their analogs, novel substrates as well as the extended/improved McMurry reac-tion are reviewed.

Key words: McMurry reaction, reductive coupling, organic synthesis, low valent titanium