有机化学 ›› 2006, Vol. 26 ›› Issue (01): 103-106. 上一篇    下一篇

研究简报

一种快速高效分解1,1-二乙酸酯的方法

靳通收*,赵莹,刘利宾 李同双   

  1. (河北大学化学与环境科学学院 保定 071002)
  • 收稿日期:2005-02-24 修回日期:2005-07-12 发布日期:2005-12-31
  • 通讯作者: 靳通收

Rapid and Efficient Procedure for Decomposition of 1,1-Diacetates Catalyzed by Silica Sulfate

JIN Tong-Shou*,ZHAO Ying,LIU Li-Bin,LI Tong-Shuang   

  1. (College of Chemistry and Environmental Science, Hebei University, Baoding 071002)
  • Received:2005-02-24 Revised:2005-07-12 Published:2005-12-31
  • Contact: JIN Tong-Shou

研究了硅胶硫酸酯催化下1,1-二乙酸酯的分解反应. 该方法具有操作简单、反应时间短、收率高、无污染、催化剂可回收重复使用等特点.

关键词: 硅胶硫酸酯, 1,1-二乙酸酯, 分解

A facile and efficient procedure for converting a number of 1,1-diacetates into the corresponding aldehydes was developed. The methodology used silica sulfate as catalyst. The advantages of this procedure were short time, high yield, environmental friendliness and the catalyst also inexpensive and reusable.

Key words: decomposition, 1,1-diacetates, silica sulfate