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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (02): 143-152.    下一篇

综述与进展

Heck反应最新研究进展

王宗廷*，张云山，王书超，夏道宏   

  1. (中国石油大学(华东)化学化工学院重质油加工国家重点实验室 东营 257062)
  • 收稿日期:2005-08-17 修回日期:2005-12-06 发布日期:2007-01-30
  • 通讯作者: 王宗廷

Recent Progress in Heck Reaction

WANG Zong-Ting*, ZHANG Yun-Shan, WANG Shu-Chao, XIA Dao-Hong   

  1. (State Key Laboratory of Heavy Oil Processing, School of Chemistry and Chemical Engineering,
    China University of Petroleum (East China), Dongying 257062)
  • Received:2005-08-17 Revised:2005-12-06 Published:2007-01-30
  • Contact: WANG Zong-Ting

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被引次数

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Heck反应是一类重要的卤代芳烃烯基化、形成新的C—C键的合成反应, 近几年来一直是催化化学和有机化学的研究热点. 总结了最近几年来国内外Heck反应新型催化体系、不对称Heck反应、Heck反应在有机合成中的最新应用等重要研究成果, 希望引起同行对Heck反应的关注.

关键词: Heck反应, 应用, 钯, 不对称合成, 催化

Heck reaction is a sort of classical methodology of the vinylation of aryl halides for the construction of new C—C bond. The new efficient catalysts for Heck reaction and the applications in whole synthesis of natural production have been developed greatly these years. In this paper, the recent progress in Heck coupling reaction including catalytic systems, asymmetric syntheses and applications in organic chemistry is reviewed.

Key words: palladium, application, catalysis, asymmetric synthesis, Heck reaction