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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (03): 313-321. 上一篇    下一篇

综述与进展

[60]富勒烯[2＋2]环加成反应的研究进展

朱玉兰*,a,b，周书雨b，曹丽a，阚玉和a   

  1. (a淮阴师范学院化学系 江苏省低维材料化学重点建设实验室 淮安 223001)
    (b延边大学理学院化学系 延吉 133002)
  • 收稿日期:2006-01-26 修回日期:2006-05-19 发布日期:2007-02-13
  • 通讯作者: 朱玉兰

Advancements and Prospects of [2＋2] Cycloaddition to [60]Fullerene

ZHU Yu-Lan*,a,b,ZHOU Shu-Yub,CAO Lia,KAN Yu-Hea   

  1. (a Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Department of Chemistry, Huaiyin Teacher's College, Huaian 223001)
    (b Department of Chemis-try, College of Science, Yanbian University, Yanji 133002)
  • Received:2006-01-26 Revised:2006-05-19 Published:2007-02-13
  • Contact: ZHU Yu-Lan

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[2＋2]环加成反应是对C60进行化学修饰的重要反应之一, 重点从[2＋2]环加成的典型反应、主要试剂及反应机理等方面进行了综述.

关键词: [60]富勒烯, [2＋2]环加成, 反应机理

[2＋2] cycloaddition plays an important role in [60]fullerene chemistry. C60 can undergo this reaction with a series of compounds containing unsaturated bonds, such as alkyne, alkene and their deriva-tives. In addition, some polymerizations of C60 also follow this route. In this review the main emphasis is on the three following aspects: classic reaction, the main reagent as well as the reaction mechanism.

Key words: reaction mechanism, [2＋2] cycloaddition, [60]fullerene