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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (01): 112-114. 上一篇    下一篇

研究简报

氢氧化铯促进下硒、端炔及二芳基碘盐反应合成炔基芳基硒醚

夏 湘a,b; 李剑平*,c ; 邹康兵a; 方大为a;
张尊英a; 徐艳丽a; 许新华*,a
  

  1. (a湖南大学化学化工学院 长沙 410082)
    (b湖南邵阳学院化学系 邵阳 422400)
    (c浙江大学医学院附属第一医院 杭州 310003)
  • 收稿日期:2008-03-27 修回日期:2008-06-18 发布日期:2009-01-20
  • 通讯作者: 李剑平;许新华

Cesium Hydroxide Promoted Reaction of Element Selenium with Terminal Alkynes and Diaryliodonium Salts to Synthesize Acetylenic Arylselenides

XIA, Xiang a,b ; LI, Jian-Ping*,c ; ZOU, Kang-Bing a; FANG, Da-Weia;
ZHANG, Zun-Yinga ; XU, Yan-Lia ; XU, Xin-Hua*,a
  

  1. (a College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082)
    (b Department of Chemistry, Shaoyang University, Shaoyang 422400)
    (c The First Affiliated Hospital, College of Medical Science, Zhejiang University, Hangzhou 310003)
  • Received:2008-03-27 Revised:2008-06-18 Published:2009-01-20
  • Contact: LI, Jian-Ping;XU, Xin-Hua

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1021

被引次数

13 | 3

以N,N-二甲基甲酰胺(DMF)作溶剂, 在4 Å分子筛存在及氮气保护下, 将端炔、CsOH、硒粉在室温搅拌2 h, 然后加入二芳基碘盐, 在0 ℃搅拌30 h, 得炔硒醚, 收率约60%.

关键词: 氢氧化铯, 炔硒醚, 二芳基碘盐, 硒

In the presence of 4Å MS, using N,N-dimethylformamide (DMF) as solvent, a mixture of terminal acetylene, cesium hydroxide and element selenium was stirred under N2 atomsphere at room temperature for 2 h, then diaryliodonium salts were added and the resulting mixture was stirred at 0 ℃ for 30 h to give acetylenic selenides in about 60% yields .

Key words: acetylenic selenide, cesium hydroxide, diaryliodonium salt, selenium