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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (07): 981-987. 上一篇    下一篇

综述与进展

碱性离子液体在有机合成中的应用研究进展

钟涛12，乐长高*1，谢宗波1，曹霞1，吕雪霞1   

  1. (1东华理工大学化学生物与材料科学学院 抚州 344000)
    (2武警黄金第一支队 牡丹江 157021)
  • 收稿日期:2009-06-17 修回日期:2009-09-01 发布日期:2009-12-30
  • 通讯作者: 钟涛 E-mail:zt20311@163.com
  • 基金资助:

    国家自然科学基金(No. 20862001)、教育部新世纪优秀人才支持计划(No. NCET-08-0701)、江西省自然科学基金(No. 2008GZH0055).

Progress in the Application of Basic Ionic Liquids to Organic Synthesis

Zhong Tao12 Le Zhangao*1 Xie Zongbo1 Cao Xia1 Lü Xuexia1   

  1. (1Faculty of Chemistry Biology and Material Science, East China Institute of Technology, Fuzhou 344000) (2Gold Geological Detachment No.1 of Chinese People s Armed Police Force, Mudanjiang 157021)
  • Received:2009-06-17 Revised:2009-09-01 Published:2009-12-30
  • Contact: ZHONG Tao E-mail:zt20311@163.com

PDF

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被引次数

73 | 12

介绍了碱性离子液体特点及其分类, 综述了近年来碱性离子液体作为催化剂和反应介质在有机合成反应的最新研究成果. 主要包括: Michael加成、Mannich反应、Knoevenagel 缩合、Markovnikov加成、Henry反应、Perkin反应、Heck偶联反应、烷基化、羰基化反应和“中断性”Feist-Benary反应.

关键词: 碱性离子液体, 催化, 有机合成, 应用

The classification and properties of basic ionic liquids are summarized. The advanced progress in the application of basic ionic liquids as reaction medium as well as catalyst to organic synthesis is reviewed, mainly including Michael addition, Mannich reaction, Knoevenagel condensation, Markovnikov addition, Henry reaction, Perkin reaction, Heck coupling reaction, alkylation, carbonylation and interrupted Feist-Benary reaction.

Key words: basic ionic liquid, catalysis, organic synthesis, application