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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (07): 986-996. 上一篇    下一篇

综述与进展

绿色化学试剂过氧化氢在有机合成中的应用研究进展

刘洋2，曾庆乐*,1,2，唐红艳2，高珊2，杨治仁2，张颂2，刘建川2   

  1. (1成都理工大学油气藏地质及开发工程国家重点实验室 成都 610059)
    (2成都理工大学材料与化学化工学院 成都 610059)
  • 收稿日期:2010-07-08 修回日期:2010-10-25 发布日期:2010-12-30
  • 通讯作者: 曾庆乐 E-mail:qinglezeng@hotmail.com

Progress on Organic Synthesis Using Hydrogen Peroxide as a Green Chemical Reagent

Liu Yang2 Zeng Qingle*,1,2 Tang Hongyan2 Gao San2 Yang Zhiren2 Zhang Song2 Liu Jiangchuan2   

  1. (1 State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu University of Technology, Chengdu 610059)
    (2 College of Materials, Chemistry and Chemical En-gineering, Chengdu University of Technology, Chengdu 610059)
  • Received:2010-07-08 Revised:2010-10-25 Published:2010-12-30
  • Contact: Qingle Zeng E-mail:qinglezeng@hotmail.com

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被引次数

52 | 2

综述了近十年来绿色化学试剂过氧化氢在合成亚砜、砜、环氧化物、醇、酚、醛、酮、酸、酯、卤代物等各种有机化合物中的研究进展, 也论述了一些新的合成反应介质体系, 如离子液体、氟相、超临界流体等绿色介质与过氧化氢结合在有机合成中的应用, 希望能促进绿色化学技术的研究与应用, 促进化学的可持续发展.

关键词: 绿色化学, 过氧化氢, 有机合成, 进展, 离子液体, 氟相, 超临界流体, 环境保护

The developments of organic synthesis using hydrogen peroxide as a green chemical reagent are reviewed in synthesizing various organic compounds, such as sulfoxides, sulfones, epoxy compounds, alcohols, phenols, aldehydes, ketones, carboxylic acids, esters and halides in recent ten years. The applications of hydrogen peroxide combining with some new classes of green reaction media including ionic liquids, fluorous phase solvents, and supercritical fluids in organic synthesis have also been described. We hope that more green technologies using hydrogen peroxide in place of unsustainable ones could be worked out and applied.

Key words: green chemistry, hydrogen peroxide, organic synthesis, progress, ionic liquid, fluorous phase, supercritical fluid, environment protection