关键词: 微波辐射, 酶, 耦合反应, 催化反应, 反应机理

Microwave irradiation and enzymatic catalysis are two powerful tools in modern organic syntheses. A new trend in catalyzing organic syntheses is to utilize these two means simultaneously, which can be called microwave irradiation-enzyme coupling catalysis (MEECC). MIECC technique can be divided into two categories such as enzymatic synthesis under microwave irradiation in non/micro-aqueous media (wet method) and without media (dry method) . The recent progress in this research field is reviewed and the typical MIECC reactions are highlighted. The mechanism of MIECC, especially the microwave-induced "athermal action" in bio-catalysis systems is briefly discussed theoretically. The potential application of MIECC is prospected.

Key words: MICROWAVE RADIATION;ENZYME;COUPLING REACTION;CATALYTIC REACTION, REACTION MECHANISM