有机化学 ›› 2003, Vol. 23 ›› Issue (4): 375-379. 上一篇    下一篇

研究论文

3-氧杂多氟戊磺酸催化羧酸的酯化反应及其铜(Ⅱ)盐催化芳烃的Friedel-Crafts酰基化反应

李桂龙;赵刚   

  1. 湖南大学化学化工学院;中国科学院上海有机化学研究所
  • 发布日期:2003-04-25

Esterificafion Catalyzed by 3-Oxa-polyfluoropentane Sulforinc Acid and Friedel-Crafts Acylation Promoted by Its Cu(Ⅱ) Salt

Li GuiLong;Zhao Gang   

  1. Department of Chemistry, Hunan University;Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
  • Published:2003-04-25

研究使用催化量的3-氧杂多氟戊磺酸催化等摩尔的羧酸和醇的酯化反应和催化 量3-氧杂多氟戊磺酸铜催化芳烃的Friedel-Crafts酰基化反应,并取得较好结果.

关键词: 磺酸 P, 氟化合物, 羧酸, 酯化, 催化反应

The esterification of carboxylic acids with equimolar of alcohols catalyzed by 3-oxa-polyfluoropentane sulfonic acid and the Friedel- Crafts acylation catalyzed by copper (II) salt of 3-oxa- polyfluoropentane sulibnic acid were studied, and good results were obtained.

Key words: SULFONIC ACID P;FLUORINE COMPOUNDS;CARBOXYLIC ACID;ESTERIFICATION, CATALYTIC REACTION

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